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2212-69-3

Articles about 2212-69-3Total 3 be found

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SULFOXONIUM YLIDE DERIVATIVES AS PROBES FOR CYSTEINE PROTEASE
The present invention relates to compounds of formula I bearing a sulfoxonium ylide moiety as warhead, or salts thereof. Such compounds can be used as activity-based probes for cysteine proteases such as cathepsin X, in methods of detecting cysteine protease activity and in related diagnostic or therapeutic methods.
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Paragraph 0389-0391

(2020/07/14)

Fairly marked enantioselectivity for the hydrolysis of amino acid esters by chemically modified enzymes
The hydrolysis (deacylation) of enantiomeric substrates by the chemically modified enzymes decanoyl-α-chymotrypsin and decanoyl-trypsin was studied. Reaction activity for decanoyl-α-chymotrypsin was lower than that for the native enzyme, although intriguingly the enantioselectivity was markedly enhanced as compared with the native enzyme. In particular, the apparently complete enantioselective catalysis was attained for the hydrolytic cleavage of p-nitrophenyl N-dodecanoyl- D(L)-phenylalaninates. The enhancement of enantioselectivity, however, was not observed for decanoyl-trypsin. These results suggest that the chemically modified α-chymotrypsin by addition of hydrophobic groups has promoted enantioselectivity for the hydrolysis of hydrophobic esters.
Yano, Yoshihiro,Shimada, Kenji,Okai, Jiro,Goto, Koichi,Matsumoto, Yoko,Ueoka, Ryuichi
p. 1314 - 1318
(2007/10/03)

Use of the 4-methoxy-2,6-dimethylbenzenesulfonyl (Mds) group to synthesize dynorphin [1-13] and related peptides
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Wakimasu,Kitada,Fujino
p. 2592 - 2597
(2007/10/02)

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Chemical Properties

Melting Point: 93.5-94.5 °C
Boiling Point: 676.9 °C at 760 mmHg
Flash Point:363.2 °C
Density: 1.234g/cm³
Storage Temp.:2-8°C
Vapor Pressure: 3.5E-18mmHg at 25°C
Refractive Index: 1.554
PKA: 10.61±0.46(Predicted)
PSA: 148.78000
LogP: 5.79520

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