- Polymer chemistry. Part V. γ-Ray induced telomerisation reactions involving 1,1-difluoroethene and hexafluoropropene
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Telomerisation reactions have been investigated for the alkenes 1,1-difluoroethene (5) and hexafluoropropene (3) with the telogens CF2Br2 (1), CF3CFBr2 (8) and CF3CBr3 (9), as a means of preparing telomers and co-telomers.The efficiency of chain transfer increases as 1 /= 8 9.Surprinsingly, co-telomerisations of 5 with 3 occurred more efficiently than the corresponding telomerisations with 5 alone.The effects of solvent are described. - Keywords: Telomerisation; γ-Ray induction; 1,1,-Difluoroethene; Hexafluoropropene; NMR spectroscopy; Mass spectrometry
- Chambers, Richard D.,Proctor, Lee D.,Caporiccio, Gerardo
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p. 241 - 248
(2007/10/02)
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