MECHANISM OF FORMATION OF TOXISTEROLS OF THE 9,10-SECOSTEROID STRUCTURE
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Orlov, A. I.,Mikhailova, N. P.,Andreev, A. V.,V'yunov, K. A.
p. 162 - 168
(2007/10/02)
Structure and Chemistry of ?-Allyl Palladium Complexes from Steroids
The synthesis and structures of ?-allyl palladium complexes prepared from vitamins D2 and D3 and from ergosterol, 7,8-didehydrocholesterol, and 3-epi-cholesterol are described.The mechanism of palladisation is descussed as well as the transformation of the complexes into conjugated trienes or allylic alcohols.