- Selective Mechanochemical Monoarylation of Unbiased Dibromoarenes by in Situ Crystallization
-
Palladium-catalyzed Suzuki-Miyaura cross-coupling reactions of liquid, unbiased dibromoarenes under mechanochemical conditions selectively afford the monoarylated products. The lower reactivity of the crystalline monoarylated products relative to the liquid starting materials should be attributed predominantly to the low diffusion efficiency of the former in the reaction mixture, which results in a selective monoarylation. The present study sheds light on a novel approach using in situ phase transitions in solids to design selective organic transformations that are difficult to achieve via conventional solution-based synthesis.
- Seo, Tamae,Kubota, Koji,Ito, Hajime
-
supporting information
p. 9884 - 9889
(2020/05/19)
-
- A threonine turnstile defines a dynamic amphiphilic binding motif in the AAA ATPase p97 allosteric binding site
-
The turnstile motion of two neighboring threonines sets up a dynamic side chain interplay that can accommodate both polar and apolar ligands in a small molecule allosteric protein binding site. A computational model based on SAR data and both X-ray and cr
- Burnett, James C.,Lim, Chaemin,Peyser, Brian D.,Samankumara, Lalith P.,Kovaliov, Marina,Colombo, Raffaele,Bulfer, Stacie L.,LaPorte, Matthew G.,Hermone, Ann R.,McGrath, Connor F.,Arkin, Michelle R.,Gussio, Rick,Huryn, Donna M.,Wipf, Peter
-
supporting information
p. 4096 - 4114
(2017/07/10)
-
- Platinum-catalyzed C-H arylation of simple arenes
-
This report describes the Na2PtCl4 catalyzed C-H arylation of arene substrates with diaryliodonium salts. The site selectivity of these reactions is predominantly controlled by steric factors. Remarkably, Na2PtCl4-catalyzed naphthalene arylation proceeds with opposite site selectivity compared to that obtained with Na2PdCl 4 as the catalyst. Preliminary mechanistic studies provide evidence for a PtII/PtIV catalytic cycle involving rate-limiting C-C bond-forming reductive elimination.
- Wagner, Anna M.,Hickman, Amanda J.,Sanford, Melanie S.
-
p. 15710 - 15713
(2013/11/06)
-
- ORGANIC ELECTROLUMINESCENCE DEVICE AND ANTHRACENE DERIVATIVE
-
An anthracene derivative having a specific asymmetric structure is provided. The asymmetric anthracenes are useful in an organic electroluminescence device and exhibit efficient light emission and a long performance lifetime.
- -
-
Page/Page column 25
(2011/02/26)
-
- PHENANTHRENE DERIVATIVE, AND MATERIAL FOR ORGANIC EL ELEMENT
-
A phenanthrene derivative is represented by a formula (1) below. In the formula (1), Ar1 and Ar2 each represent an aromatic hydrocarbon ring group having 6 to 18 carbon atoms for forming the ring. The aromatic hydrocarbon ring group contains none of anthracene skeleton, pyrene skeleton, aceanthrylene skeleton and naphthacene skeleton. R1 represents a substituent, the number of which may be 0, 1 or more. R1 may be bonded in any position of the phenanthrene skeleton. n and m each represent an integer of 1 to 3. k represents an integer of 0 to 8.
- -
-
Page/Page column 94-95
(2011/01/11)
-
- NAPHTHALENE DERIVATIVE, MATERIAL FOR ORGANIC ELECTROLUMINESCENCE DEVICE, AND ORGANIC ELECTROLUMINESCENCE DEVICE USING THE SAME
-
A naphthalene derivative represented by the following formula (1) is provided. In the formula, Ar1 to Ar4 each represent an aromatic hydrocarbon cyclic group having 6 to 18 carbon atoms forming a ring. The aromatic hydrocarbon cyclic group has none of anthracene skeleton, pyrene skeleton, aceanthrylene skeleton and naphthacene skeleton. n, m and 1 each represent an integer in a range of 1 to 5. p represents an integer in a range of o to 5. When n, m, 1 and p each are 2 or more, a plurality of Ar1 to Ar4 may be mutually the same or different.
- -
-
-
- ORGANIC ELECTROLUMINESCENCE DEVICE AND ANTHRACENE DERIVATIVE
-
An organic electroluminescence device which comprises a cathode, an anode and an organic thin film layer comprising at least one layer comprising a light emitting layer and disposed between the cathode and the anode, wherein at least one layer in the organic thin film layer comprises an anthracene derivative having a specific structure singly or as a component of a mixture, and an anthracene derivative having a specific asymmetric structure and providing an organic electroluminescence device exhibiting a great efficiency of light emission and having a long life, are provided.
- -
-
-
- ANTHRACENE DERIVATIVES, ORGANIC ELECTRONIC DEVICES USING ANTHRACENE DERIVATIVES, AND ELECTRONIC APPARATUSES COMPRISING ORGANIC ELECTRONIC DEVICE
-
Disclosed is an anthracene derivative, an organic electronic device using the anthracene derivative, and an electronic apparatus including the organic electronic device. The anthracene derivative is capable of being used as a hole injecting material, a hole transporting material, an electron injecting material, an electron transporting material, and a light emitting material in an organic electronic device including an organic light emitting device. In particular, the anthracene derivative is capable of being used alone as a light emitting material and a host or a dopant in a host/dopant system. The organic electronic device is excellent in views of efficiency, driving voltage, life time, and stability.
- -
-
Page/Page column 14-15
(2010/11/30)
-
- NEW ANTHRACENE DERIVATIVES, PREPARATION METHOD THEREOF AND ORGANIC LIGHT EMITTING DIODE USING THE SAME
-
The present invention provides a novel anthracene derivative, a method for preparing the same, and an organic electronic device using the same. The anthracene derivative according to the invention can function alone as a light emitting host, in particular, as a blue host in an organic electronic device. Further, the anthracene derivative according to the invention can also function as a hole injecting or hole transporting material, an electron injecting or electron transporting material, or a light emitting material in an organic electronic device including a light emitting device. Therefore, the organic electronic device according to the present invention shows excellent characteristics in efficiency, drive voltage and stability.
- -
-
Page/Page column 72
(2010/11/28)
-
- ASYMMETRIC MONOANTHRACENE DERIVATIVE, MATERIAL FOR ORGANIC ELECTROLUMINESCENT DEVICE AND ORGANIC ELECTROLUMINESCENT DEVICE UTILIZING THE SAME
-
Provided are an asymmetric monoanthracene derivative having a specific structure, a material for an organic EL device comprising the above asymmetric monoanthracene derivative and an organic EL device in which an organic thin film layer comprising a single layer or plural layers including a luminescent layer is interposed between a cathode and an anode, wherein at least one of the above organic thin film layers contains the asymmetric monoanthracene derivative described above in the form of a single component or a mixed component. Provided are an organic electroluminescent (EL) device having a high luminous efficiency and a long life, an asymmetric monoanthracene derivative which materializes the same and a material for an organic EL device.
- -
-
Page/Page column 35
(2008/06/13)
-