Enantiospecific synthesis of some bioactive amino alcohols and related compounds from cyclohexylideneglyceraldehyde
Two bioactive amino alcohols or related derivatives, 2-aminohexadecanol I and erythro-9-(2-hydroxy-3-nonyl)adenine hydrochloride (EHNA hydrochloride) IIa, have been synthesized from some enantiomerically pure 3-alkylglycerols. The required C-3 epimeric 3-
Sharma, Anubha,Chattopadhyay, Subrata
p. 883 - 890
(2011/07/06)
Synthesis of Inhibitors of Adenosine Deaminase. A Total Synthesis of erythro-3-(Adenin-9-yl)-2-nonanol and Its Isomers from Chiral Precursors
The synthesis of both isomers of EHNA2 ("erythrohydroxynonyladenine") from D- and L-rhamnose is described.The key intermediates, (R)- and (S)-2-(benzyloxy)propanal, derived respectively from 5-O-benzyl-D- and -L-rhamnitol, were each condensed w
Baker, David C.,Hawkins, L. D.
p. 2179 - 2184
(2007/10/02)
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