Preparation of Unsymmetrical Methyl/Phenylcarbodiphosphoranes Through Stepwise Synthesis or Rearrangement
The bis-phosphonium salt 1,2-C6H4(PPh2Me+SO3F-)2 (8), obtained from the double quaternisation of 1,2-bis(diphenylphosphino)benzene (6) using CH3OSO2F, yields on transylidation with excess Et3P=CHMe as an unexpected rearrangement prod
Schmidbaur, Hubert,Herr, Rudolf,Zybill, Christian E.
p. 3374 - 3380
(2007/10/02)
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