Tetrahedron Letters p. 7123 - 7126 (1991)
Update date:2022-09-26
Topics:
Hall
Sevin
Warren
Alkenes having a diphenylphosphinoyl group on a chiral centre next to an allylic alcohol and epoxidised with double diastereomeric induction, all erythro isomers giving epoxidation syn to the OH group regardless of other chiral centres. The products are developed into transposed Z allylic alcohols with 1,4-related chiral centres.
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