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Scheme 4. Attempted Synthesis of 1 through Isonitrile/HOBt-
Mediated Couplings
́
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Scheme 5. Epimerization Mechanism
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congeners are in progress.
ASSOCIATED CONTENT
* Supporting Information
General experimental procedures, including spectroscopic and
analytical data for new compounds. This material is available free
■
S
AUTHOR INFORMATION
Corresponding Author
■
Notes
The authors declare no competing financial interest.
ACKNOWLEDGMENTS
This research was supported by NIH Grant CA103823 (S.J.D.).
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