Journal of the American Chemical Society p. 6599 - 6603 (1981)
Update date:2022-08-05
Topics:
McDonald, Richard N.
Chowdhury, A. Kasem
Setser, D. W.
Phenylnitrene anion radical (PhN-.) was prepared in a flowing afterglow apparatus by dissociative electron attachement of phenyl azide (PhN3).PhN-. undergoes a very slow reaction with PhN3, producing PhN4Ph-. and PhN2Ph-. in a ratio of 4:1.The proton affinity pf PhN-. was bracketed from kinetic studies with various potential proton donors, PA(PhN-.) = 372 +/- 2 kcal mol-1, from which ΔHf0(PhN-.) = 60 +/- 2 kcal mol -1 was calculated.With alcohols which are too weakly acidic to directly protonate PhN-.
Xi'an North Information Industry Co., Ltd. Weilv Chemical Department
Contact:+86-29-88156413
Address:Jixiang Road 99 Xi'an Shaanxi Province
Yueyang Hudex Pharmaceuticals Ltd.
Contact:0730-8748800
Address:Wujiang Bridge,Yueyang Economy & Technology Development Zone
Beijing ZhongDaXinHe Chemical Product Co.,Ltd
Contact:010-52876516
Address:tongzhoubeiyuan
Suzhou Howsine Biological Technology Co.,Ltd
website:http://www.howsine.com
Contact:86-512-67262751
Address:No 3,Weihua Road ,Suzhou Industrial Park ,Jiangsu ,China.
Hangzhou Dawn Ray Pharmaceutical Co.,Ltd
website:http://www.dawnraypharma.com/
Contact:+86-571-85335020
Address:1018 Guangyin Building,No.42 E.Fengqi Road,Hangzhou,310012 China
Doi:10.1002/ardp.19332710606
(1933)Doi:10.1021/jo01336a017
(1979)Doi:10.1016/S0040-4039(01)86092-5
(1979)Doi:10.1021/ja00512a037
(1979)Doi:10.1021/jo00393a032
(1979)Doi:10.1021/ol062655w
(2007)