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Russ.Chem.Bull., Int.Ed., Vol. 64, No. 3, March, 2015
Kopchuk et al.
(m, 1 H); 8.70—8.74 (m, 1 H); 8.78 (d, 1 H, pyridine, J = 8.2 Hz);
9.54—9.59 (m, 1 H, H(8)). 13C NMR (CDCl3), : 26.0, 33.7,
37.3, 121.7, 122.3, 123.2, 123.3, 126.2, 126.5, 127.1, 127.2, 127.3,
127.6, 127.7, 128.2, 128.3, 129.7, 130.2, 130.8, 131.2, 131.9,
135.1, 139.0, 139.1, 140.4, 140.7, 145.0, 149.7, 151.8, 155.6,
157.3. MS (ESI), m/z (%): 499.22 [M + H]+ (100).
1ꢀ(5,6ꢀDiphenylpyridinꢀ2ꢀyl)ꢀ3ꢀphenylꢀ6,7ꢀdihydroꢀ5Hꢀcycloꢀ
penta[c]pyridine (8b). Ethanol was used as the solvent. The yield
was 75 mg (72%), m.p. 152—154 C. Found (%): C, 87.54;
H, 5.61; N, 6.47. C31H24N2. Calculated (%): C, 87.70; H, 5.70;
N, 6.60. 1H NMR (CDCl3), : 2.12—2.22 (m, 2 H, CH2(6));
3.03 (t, 2 H, CH2(7), J = 7.6 Hz); 3.61 (t, 2 H, CH2 (5), J = 7.6 Hz);
7.23—7.32 (m, 8 H, Ph); 7.38—7.44 (m, 1 H, Ph); 7.45—7.53
(m, 4 H, Ph); 7.69 (s, 1 H, H(4)); 7.88 (d, 1 H, pyridine, J = 7.7 Hz);
8.13—8.17 (m, 2 H, Ph); 8.57 (d, 1 H, pyridine, J = 7.7 Hz).
13C NMR (CDCl3), : 25.1, 32.8, 33.6, 116.5, 121.3, 126.9,
127.2, 127.6, 127.8, 128.4, 128.5, 128.6, 129.7, 130.2, 134.9,
138.2, 139.2, 140.0, 140.3, 140.6, 151.0, 154.4, 155.5, 156.9,
157.2. MS (ESI), m/z (%): 425.20 [M + H]+ (100).
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This work was financially supported by the Ministry of
Education and Science of the Russian Federation (State
Contract No. 8430), the Council on Grants at the Presiꢀ
dent of the Russian Federation (Program of State Support
for Leading Scientific Schools and Young Scientists of the
Russian Federation, Grant MKꢀ3079.2015.3), and the
Government of the Russian Federation (Program 211,
Agreement No. 02.A03.21.0006).
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Received January 27, 2015