Tetrahedron p. 4301 - 4312 (1992)
Update date:2022-08-03
Topics: Derivatives Carboxylic Acids Text format Experimental Samarium diiodide Reductions Acid system
Kamochi
Kudo
Carboxylic acid was converted to alcohol in a facile-rapid reduction using samarium diiodide in protic solvent under a basic or acidic medium at room temperature in high yield. A similar reaction of ester and anhydride reduced to the corresponding alcohol as the major products and nitrile afforded amine. Amide was rapidly reduced under a basic medium to afford alcohol, but the reduction with samarium diiodide-acid system of amide gave aldehyde in quantitative yield.
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