Tetrahedron p. 2233 - 2240 (1988)
Update date:2022-08-28
Topics:
Rudchenko, Vladimir F.
Ignatov, Sergei M.
Chervin, Ivan I.
Kostyanovsky, Remir G.
The chlorination of acyclic N,N-dialkoxyamines under the action of tert-BuOCl results in the formation of unstable N-chloro-N,N-dialkoxyamines wich in situ react with sodium methoxide to give previously unknown trialkoxyamines (orthonitrites).The properties of the N-chloro-N,N-dialkoxy- and trialkoxyamines have been demonstrated to be similar to those of their carbon analogues: dialkoxyalkylchlorides and orthoesters, respectively.
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