Tetrahedron Letters p. 6955 - 6956 (1988)
Update date:2022-08-29
Topics:
Tamao, Kohei
Maeda, Kimio
Tanaka, Tetsu
Ito, Yoshihiko
Platinum-catalyzed intramolecular hydrosilation of hydrodimethylsilyl ethers of homopropargyl alcohols proceeds regioselectively in a 5-exo-dig mode.The resulting vinylsilanes can be transformed into 3-alkanon-1-ol and 3-bromo-3-alken-1-ol derivatives by H2O2 oxidation and bromine cleavage, respectively.
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