Mendeleev Commun., 2017, 27, 416–418
the partial hydrogenation of C=C double bonds is not unusual.
Note that a melting peak appears on the DSC curve of the
reaction product at 105°C, which is close to the Tm of hydro
genated PNB.
6 M. L. Gringolts,Yu. I. Denisova, G. A. Shandryuk, L. B. Krentsel, A. D.
Litmanovich, E. Sh. Finkelshtein and Y.V. Kudryavtsev, RSC Adv., 2015,
, 316.
M. R. Radlauer, M. E. Matta and M. A. Hillmyer, Polym. Chem., 2016,
, 6269.
N. A. Platé, A. D. Litmanovich andY. V. Kudryavtsev, Polym. Sci., Ser. A,
004, 46, 1108 (Vysokomol. Soedin., Ser. A, 2004, 46, 1834).
9 H. Otsuka, K. Aotani, Y. Higaki and A. Takahara, J. Am. Chem. Soc.,
003, 125, 4064.
0 Y.X. Lu, F. Tournilhac, L. Leibler and Z. Guan, J. Am. Chem. Soc.,
012, 134, 8424.
5
7
8
7
In a few studies reported on using Grubbs’ catalysts for imple
2
4,25
menting metathesis and hydrogenation as tandem reactions,
2
the metathesis was carried out first and then hydrogen was fed into
the reactor. This resulted in the transformation of a metathesis
catalyst into a hydride complex which promoted hydrogenation
of double C=C bonds in the metathesis product. In the future, we
plan to study such processes in our system in more detail.
2
1
2
1
1 Y.X. Lu and Z. Guan, J. Am. Chem. Soc., 2012, 134, 14226.
2 C. Descour, T. Macko, I. SchreurPiet, M. P. F. Pepels and R. Duchateau,
RSC Adv., 2015, 5, 9658.
1
We are grateful to Dr. A. S. Peregudov (A. N. Nesmeyanov
Institute of Organoelement Compounds, RAS) for NMR studies
and to S. A. Korchagina (A. V. Topchiev Institute of Petro
chemical Synthesis, RAS) for GPC measurements. Yu. I. Denisova
acknowledges the support of the Russian Foundation for Basic
Research (grant no. 163360213).
13 Olefin Metathesis and Metathesis Polymerization, eds. K. J. Ivin and
J. C. Mol, Academic Press, London, 1997.
1
4 S. E. Lehman, Jr., K. B. Wagener, L. S. Baugh, S. P. Rucker, D. N. Schulz,
M. VarmaNair and E. Berluche, Macromolecules, 2007, 40, 2643.
5 C. W. Bielawski and R. H. Grubbs, Angew. Chem. Int. Ed., 2000, 39, 2903.
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2583.
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7 M. Bornand and P. Chen, Angew. Chem. Int. Ed., 2005, 44, 7909.
Online Supplementary Materials
Supplementary data associated with this article can be found
in the online version at doi: 10.1016/j.mencom.2017.07.033.
1
8 R. Walker, R. M. Conrad and R. H. Grubbs, Macromolecules, 2009, 42, 599.
9 M. A. Hillmyer, W. R. Laredo and R. H. Grubbs, Macromolecules, 1995,
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0 H. Han, F. Chen, J. Yu, J. Dang, Z. Ma, Y. Zhang and M. Xie, J. Polym.
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