Tetrahedron Letters p. 1121 - 1122 (1996)
Update date:2022-08-17
Topics:
Sarobe
Jenneskens
Wiersum
The product composition of the pyrolysates obtained upon thermolysis of the alternant C18H12 PAH benzo[c]phenanthrene (1) is markedly pressure dependent. At 0.1-0.5 Torr (N2 carrier gas, 1050-1150°C) 1 is converted into the non-alternant C18H10PAH's cyclopenta[cd]pyrene (4) and benzo[ghi]fluoranthene (5) which have been identified as abundant combustion effluents and are associated with fullerene formation.
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