Tetrahedron Letters p. 1091 - 1094 (1996)
Update date:2022-08-30
Topics:
Chiavetto, Luisella Bocchio
Guglielmetti, Gianfranco
Querci, Cecilia
Ricci, Marco
Isosafrole (1a) and isoeugenol methyl ether (1b), two closely related substrates, behave very differently when subjected to manganese porphyrins catalysed epoxidation by sodium hypochlorite. A possible explanation is given, in terms of an unusual competition between the epoxidation and the O-dealkylation of the -OCH2O-moiety.
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