Chemistry Letters p. 1409 - 1412 (1987)
Update date:2022-08-24
Topics:
Tanase, Tomoaki
Murata, Takashi
Yano, Shigenobu
Hidai, Masanobu
Yoshikawa, Sadao
Aldoses are rapidly epimerized at C-2 by combination of alkaline earth or rare earth metal ions (Ca2+, Sr2+,Pr3+, or Ce3+)and monoamines (triethlamine etc.). (13)C NMR studies using <1-(13)C>-D-glucose of the Ca2+ system revealed that this reaction proceeds via the stereospecific rearrangement of carbon skeleton.
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