Bull. Russ. Acad. Sci. Div. Chem. Sci. (Engl. Transl.) p. 1928 - 1930 (1992)
Update date:2022-08-28
Topics:
Kandror, I. I.
Galkina, M. A.
Bragina, I. O.
Lavrukhin, B. D.
Belokon', Yu. N.
Gololobov, Yu. G
Ethyl α-cyanoacrylate undergoes the Michael reaction with strong CH-acids (pKa < 13) in the presence of strong basic amines such as butylamine, piperidine, and triethylamine.Only polymerization of ethyl α-cyanoacrylate occurs under the same conditions with weaker CH-acids in the presence of less basic amines such as aniline, N-methylaniline, and pyridine.Keywords: ethyl α-cyanoacrylate, Michael reaction, CH-acids.
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