Technology Process of Antimony, difluorotriphenyl-
There total 13 articles about Antimony, difluorotriphenyl- which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
In
acetonitrile;
Electrolysis; argon atmosphere; cell with diaphragm, anode Pt beaker, cathode Pt wire,reference electrode Ag/AgNO3, anolyte Ph3Sb/Et4NBF4 soln., catholyte satd. PyHBF4 soln., current density 1.67 mA/cm**2, 1.50 Ah electricity passed, 20°C; solvent removal (vac.), residue extn. (ether), crystn. on ether removal, crystals washing (water), recrystn. (ethanol), vac.-drying (60°C); elem. anal.;
- Guidance literature:
-
In
acetonitrile;
Electrolysis; N2 atmosphere, ambient temp.; constant current electrolysis (Pt plate and wire electrodes); extraction (ether), washing of extracts (water, brine), drying (MgSO4),solvent removal, recrystn. (ethanol);
DOI:10.1016/S0013-4686(97)85470-9
- Guidance literature:
-
With
nitrosonium tetrafluoroborate;
In
dichloromethane;
at 0 - 20 ℃;
for 3h;
Reagent/catalyst;
Solvent;
DOI:10.1016/j.jfluchem.2017.04.004