Phenalenyl

Base Information

• Chemical Name: Phenalenyl
• CAS No.: 3924-44-5
• Molecular Formula: C13H9
• Molecular Weight: 165.214
• Mol file: 3924-44-5.mol

Synonyms:

Chemical Property of Phenalenyl

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Phenalenyl

There total 2 articles about Phenalenyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

naptho[1’,8a’,8’:bc]-bicyclo[3.1.0]hex-2-ene (6840-31-9) → phenalenyl (3924-44-5) + perinaphthane (479-58-3) + phenalenyl anion (42464-32-4) + 2,3-Dihydro-1H-phenalene (479-58-3)

Guidance literature:

With potassium Sodium; In tetrahydrofuran; at 25 ℃; Mechanism; other temp., solvents;

DOI:10.1021/jo00321a033

Reference yield:

phenalene (203-80-5) + isopropenylbenzene (98-83-9,6144-04-3,25014-31-7,42612-14-6) → Isopropylbenzene (98-82-8) + phenalenyl (3924-44-5)

Guidance literature:

With 1,2-dihydroanthracene; In diphenylether; at 200 ℃; Kinetics; Thermodynamic data; Mechanism; ΔG(excit.), ΔH(excit.), ΔS(excit.), also with D4-DHA;

upstream raw materials:

naptho[1’,8a’,8’:bc]-bicyclo[3.1.0]hex-2-ene

phenalene

isopropenylbenzene

Refernces

• 1、 Dodd, John R.,Pagni, Richard M.,Watson, Charles R.. "Electrocyclic Ring Opening of the 6b,7a-Dihydro-7H-cyclopropacenaphthylene Radical Anion". . p. 1688 - 1692. Retrieved 2007/10/02.