TETRABENZ[A,C,H,J]ANTHRACENE

Base Information

• Chemical Name: TETRABENZ[A,C,H,J]ANTHRACENE
• CAS No.: 215-11-2
• Molecular Formula: C30H18
• Molecular Weight: 378.473
• Hs Code.: 2902909090
• Mol file: 215-11-2.mol

Synonyms:1,2,3,4,5,6,7,8-Tetrabenzoanthracen;tetrabenzanthracene;

Chemical Property of TETRABENZ[A,C,H,J]ANTHRACENE

Chemical Property:

• Vapor Pressure: 2E-17mmHg at 25°C
• Boiling Point: 677°C at 760 mmHg
• Flash Point: 360.6°C
• PSA: 0.00000
• Density: 1.286g/cm³
• LogP: 8.60580

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of TETRABENZ[A,C,H,J]ANTHRACENE

There total 1 articles about TETRABENZ[A,C,H,J]ANTHRACENE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

3-(trimethylsilyl)triphenylenyl 2-trifluoromethanesulfonate (911197-55-2) + 2-(trimethylsilyl)phenyl trifluoromethanesulfonate (88284-48-4) → C42H24 + triphenylene (217-59-4) + phenanthro[9,10-b]triphenylene (215-11-2)

Guidance literature:

With cesium fluoride; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In tetrahydrofuran; acetonitrile; at 20 ℃; for 14h; Title compound not separated from byproducts.;

DOI:10.1002/chem.200600466

Reference yield:

phenanthro[9,10-b]triphenylene (215-11-2) → C41H25N

Guidance literature:

Multi-step reaction with 3 steps

1: N-Bromosuccinimide / dimethyl sulfoxide / 3 h / 38 °C / Inert atmosphere

2: (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium acetate / N,N-dimethyl-formamide / 5 h / 150 °C / Inert atmosphere

3: tetrakis(triphenylphosphine) palladium⁽⁰⁾; potassium carbonate / tetrahydrofuran; water / 20 h / 80 °C / Inert atmosphere

With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; N-Bromosuccinimide; tetrakis(triphenylphosphine) palladium⁽⁰⁾; potassium acetate; potassium carbonate; In tetrahydrofuran; water; dimethyl sulfoxide; N,N-dimethyl-formamide;

Reference yield:

phenanthro[9,10-b]triphenylene (215-11-2) → C47H29N

Guidance literature:

Multi-step reaction with 3 steps

1: N-Bromosuccinimide / dimethyl sulfoxide / 3 h / 38 °C / Inert atmosphere

2: (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium acetate / N,N-dimethyl-formamide / 5 h / 150 °C / Inert atmosphere

3: tetrakis(triphenylphosphine) palladium⁽⁰⁾; potassium carbonate / tetrahydrofuran; water / 20 h / 80 °C / Inert atmosphere

With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; N-Bromosuccinimide; tetrakis(triphenylphosphine) palladium⁽⁰⁾; potassium acetate; potassium carbonate; In tetrahydrofuran; water; dimethyl sulfoxide; N,N-dimethyl-formamide;

upstream raw materials:

3-(trimethylsilyl)triphenylenyl 2-trifluoromethanesulfonate

2-(trimethylsilyl)phenyl trifluoromethanesulfonate

Refernces