Methanediol, (4-methoxy-3-nitrophenyl)-, diacetate (ester)

Base Information

• Chemical Name: Methanediol, (4-methoxy-3-nitrophenyl)-, diacetate (ester)
• CAS No.: 479669-09-5
• Molecular Formula: C12H13NO7
• Molecular Weight: 283.238
• Mol file: 479669-09-5.mol

Synonyms:Acetic acid acetoxy-(4-methoxy-3-nitro-phenyl)-methyl ester;4-Diacetoxymethyl-1-methoxy-2-nitro-benzol;4-diacetoxymethyl-1-methoxy-2-nitro-benzene;

Chemical Property of Methanediol, (4-methoxy-3-nitrophenyl)-, diacetate (ester)

Chemical Property:

• PSA: 107.65000
• LogP: 2.25140

Purity/Quality:

99% ^*data from raw suppliers

(4-METHOXY-3-NITROPHENYL)METHYLENE DIACETATE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Methanediol, (4-methoxy-3-nitrophenyl)-, diacetate (ester)

There total 3 articles about Methanediol, (4-methoxy-3-nitrophenyl)-, diacetate (ester) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 64.0%

acetic anhydride (108-24-7) + 4-methoxy-benzaldehyde (123-11-5) → 4-methoxybenzaldehyde-1,1-diacetate (14202-31-4) + (4-methoxy-3-nitrophenyl)methylene diacetate (479669-09-5)

Guidance literature:

With lithium nitrate; scandium tris(trifluoromethanesulfonate); In acetonitrile; at 20 ℃; for 4h;

DOI:10.1248/cpb.50.1060

Reference yield:

acetic anhydride (108-24-7) + 4-methoxy-benzaldehyde (123-11-5) → (4-methoxy-3-nitrophenyl)methylene diacetate (479669-09-5)

Guidance literature:

With nitric acid; at -10 ℃;

Reference yield:

acetic anhydride (108-24-7) + 4-methoxy-3-nitrobenzaldehyde (31680-08-7) → (4-methoxy-3-nitrophenyl)methylene diacetate (479669-09-5)

Guidance literature:

upstream raw materials:

acetic anhydride

4-methoxy-benzaldehyde

4-methoxy-3-nitrobenzaldehyde

Downstream raw materials:

Cresidine

Refernces