1-phenylpyrene

Base Information

• Chemical Name: 1-phenylpyrene
• CAS No.: 5101-27-9
• Molecular Formula: C22H14
• Molecular Weight: 278.353
• Mol file: 5101-27-9.mol

Synonyms:

Chemical Property of 1-phenylpyrene

Chemical Property:

• Vapor Pressure: 3.01E-08mmHg at 25°C

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1-phenylpyrene

There total 24 articles about 1-phenylpyrene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

1-bromopyrene (1714-29-0) + phenylboronic acid (98-80-6) → 1-phenyl pyrene (5101-27-9)

Guidance literature:

1-bromopyrene; phenylboronic acid; With sodium methylate; In ethanol; Inert atmosphere;

In ethanol; at 60 ℃; for 1h; Inert atmosphere;

DOI:10.1016/j.jcat.2021.04.016

Reference yield: 85.0%

para-diiodobenzene (624-38-4,1032416-46-8) + 1-pyrenylboronic acid (164461-18-1) → 1,1'-(1,4-phenylene)bis-pyrene + 1-phenyl pyrene (5101-27-9)

Guidance literature:

With bis-triphenylphosphine-palladium(II) chloride; dichloro bis(acetonitrile) palladium(II); In tetrahydrofuran; at 70 ℃;

DOI:10.1002/jccs.201100557

Reference yield: 83.0%

bromobenzene (108-86-1,52753-63-6) + 1-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)pyrene (349666-24-6) → 1-phenyl pyrene (5101-27-9)

Guidance literature:

With sodium carbonate; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In toluene; Heating;

DOI:10.1002/1099-0690(200110)2001:20<3819::AID-EJOC3819>3.0.CO;2-W

upstream raw materials:

pyrene

phenyl radical

acetone

phenalene

Refernces

• 1、 Ganguly, Saheli,Paul, Sibasish,Yehezkeli, Omer,Cha, Jennifer,Caruthers, Marvin H.. "Boranephosphonate DNA-Mediated Metallization of Single-Walled Carbon Nanotubes". . p. 2239 - 2245. Retrieved 2017.
• 2、 Crocker, Reece D.,Dinh, An H.,Lyons, Demelza J. M.,Mai, Binh Khanh,Nguyen, Thanh Vinh,Ton, Nhan N. H.. "Ring Contraction of Tropylium Ions into Benzenoid Derivatives". supporting information. p. 2520 - 2525. Retrieved 2022/04/12.