Technology Process of 1-Heptyne, 3-ethyl-
There total 1 articles about 1-Heptyne, 3-ethyl- which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
Br2Cu(1-)*Li(1+);
Yield given. Multistep reaction. Yields of byproduct given. Title compound not separated from byproducts;
1.) THF, -50 deg C, 30 min, 2.) THF, -70 deg C, 30 min;
DOI:10.1016/0022-328X(91)80179-N
- Guidance literature:
-
3-ethyl-1-heptyne; Tetraphenyldiphosphin;
With
2,4-dimethylnitrobenzene;
rhodium hydrido (PEt3)3 complex;
In
toluene;
for 5h;
Heating;
With
dihydrogen peroxide;
In
tetrahydrofuran; water; toluene;
at 0 ℃;
for 1h;
DOI:10.1016/j.tetlet.2006.04.158
- Guidance literature:
-
3-ethyl-1-heptyne;
With
isopropylmagnesium chloride;
In
tetrahydrofuran;
at 20 - 60 ℃;
for 2h;
Inert atmosphere;
benzo[1,2-b:4,5-b']dithiophene;
In
tetrahydrofuran;
at 60 ℃;
for 2h;
Inert atmosphere;
With
hydrogenchloride; tin(ll) chloride;
In
tetrahydrofuran; water;
at 20 ℃;
Inert atmosphere;
DOI:10.1021/cm2038427