4-Nonene

Base Information

• Chemical Name: 4-Nonene
• CAS No.: 2198-23-4
• Molecular Formula: C₉H₁₈
• Molecular Weight: 126.242
• European Community (EC) Number: 218-595-2
• DSSTox Substance ID: DTXSID4075451
• Mol file: 2198-23-4.mol

Synonyms:4-Nonene;Non-4-ene;2198-23-4;non-5-ene;4-Nonene,c&t;4-Nonene (cis & trans);DTXSID4075451;EINECS 218-595-2;FT-0619314;FT-0694913;N0386;D91694

Chemical Property of 4-Nonene

Chemical Property:

• Vapor Pressure: 6.06mmHg at 25°C
• Melting Point: -89.14°C (estimate)
• Refractive Index: n20/D 1.419
• Boiling Point: 144-146 °C(lit.)
• Flash Point: 81 °F
• PSA: 0.00000
• Density: 0.732 g/mL at 25 °C(lit.)
• LogP: 3.53290
• Storage Temp.: 2-8°C
• XLogP3: 4.2
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 5
• Exact Mass: 126.140850574
• Heavy Atom Count: 9
• Complexity: 62.4

Purity/Quality:

99% ^*data from raw suppliers

4-Nonene (cis- and trans- mixture) >99.0%(GC) ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xn
• Statements: 10-65
• Safety Statements: 16-62

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: CCCCC=CCCC

Technology Process of 4-Nonene

There total 73 articles about 4-Nonene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

pentanal (110-62-3) + n-butyl(triphenyl)phosphonium bromide (1779-51-7) → (E)-non-4-ene (10405-85-3,2198-23-4) + Triphenylphosphine oxide (791-28-6)

Guidance literature:

With potassium carbonate; formamide; In 1,4-dioxane; at 95 ℃; for 2.5h;

Reference yield: 70.0%

di-n-butyl-malonyl peroxide (30842-78-5) → (E)-non-4-ene (10405-85-3,2198-23-4) + nonanone-5 (502-56-7)

Guidance literature:

In gas; at 450 ℃; under 0.6 Torr; Yields of byproduct given;

DOI:10.1016/S0040-4039(01)90274-6

Reference yield: 35.0%

5-nonanol (623-93-8) → nonane (111-84-2) + (E)-non-4-ene (10405-85-3,2198-23-4)

Guidance literature:

With aluminum tri-bromide; triisobutylaluminum; diisobutylaluminium hydride; bis(acetylacetonate)nickel(II); zirconocene dichloride; multistep reaction, reductive deoxygenation;

DOI:10.1021/jo00033a041

upstream raw materials:

pentanal

E/Z-1,3-Dichloropropene

n-propylmagnesium bromide

5-nonanol

Downstream raw materials:

nonane

4-octene

(E)-non-4-ene

5-decene

Refernces

• 1、 Bedzyk, Michael J.,Das, Anusheela,Kratish, Yosi,Li, Jiaqi,Ma, Qing,Marks, Tobin J.. "Diverse Mechanistic Pathways in Single-Site Heterogeneous Catalysis: Alcohol Conversions Mediated by a High-Valent Carbon-Supported Molybdenum-Dioxo Catalyst". . p. 1247 - 1257. Retrieved 2022/02/07.
• 2、 Zhizhko, Pavel A.,Mougel, Victor,De Jesus Silva, Jordan,Copéret, Christophe. "Benchmarked Intrinsic Olefin Metathesis Activity: Mo vs. W". . . Retrieved 2018/02/28.