Methanol, 1,1'-oxybis-, 1,1'-diMethanesulfonate

Base Information

• Chemical Name: Methanol, 1,1'-oxybis-, 1,1'-diMethanesulfonate
• CAS No.: 62609-70-5
• Molecular Formula: C4H10O7S2
• Molecular Weight: 234.251
• Mol file: 62609-70-5.mol

Synonyms:Methanol,oxybis-,dimethanesulfonate;bis-methanesulfonyloxymethyl ether;methanesulfonic acid 2-oxa-propane-1,3-diyl ester;

Chemical Property of Methanol, 1,1'-oxybis-, 1,1'-diMethanesulfonate

Chemical Property:

• PSA: 175.19000
• LogP: 0.07220

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Methanol, 1,1'-oxybis-, 1,1'-diMethanesulfonate

There total 2 articles about Methanol, 1,1'-oxybis-, 1,1'-diMethanesulfonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1,3,5-Trioxan (110-88-3) + Acetyl methanesulfonate (5539-53-7) → diacetoxymethane (628-51-3,25231-38-3) + bis-methanesulfonyloxymethyl ether (62609-70-5)

Guidance literature:

at 60 - 65 ℃; for 2h;

Reference yield:

1,3,5-Trioxan (110-88-3) + Acetyl methanesulfonate (5539-53-7) → bis-methanesulfonyloxymethyl ether (62609-70-5)

Guidance literature:

DOI:10.1021/jo00437a028

Reference yield: 53.0%

isonicotinamide (1453-82-3) + bis-methanesulfonyloxymethyl ether (62609-70-5) + O-acetyl-2-pyridinecarboxaldoxime (74231-53-1,19433-10-4) → C14H16N4O3(2+)*2CH3O3S(1-) + 1-[[[4-(aminocarbonyl)pyridino]methoxy]methyl]-2-[(hydroxyimino)methyl]pyridinium bis-methanesulfonate

Guidance literature:

bis-methanesulfonyloxymethyl ether; O-acetyl-2-pyridinecarboxaldoxime; In dichloromethane; acetonitrile; for 6h;

isonicotinamide; In dichloromethane; N,N-dimethyl-formamide; acetonitrile; for 17h;

With ethanol; for 6h; Product distribution / selectivity;

upstream raw materials:

1,3,5-Trioxan

Acetyl methanesulfonate

Downstream raw materials:

di-n-butyloxymethane

Refernces

• 1、 -. "SYNTHESIS". Page/Page column 8-9. . Retrieved 2008/12/07.