potassium piperidine-1-dithiocarboxylate

Base Information

• Chemical Name: potassium piperidine-1-dithiocarboxylate
• CAS No.: 136-04-9
• Molecular Formula: C6H11 N S2 . K
• Molecular Weight: 199.382
• Hs Code.: 2933399090
• Mol file: 136-04-9.mol

Synonyms:1-Piperidinecarbodithioicacid, potassium salt (8CI,9CI); Potassium pentamethylenedithiocarbamate;Potassium piperidine-1-carbodithioate

Chemical Property of potassium piperidine-1-dithiocarboxylate

Chemical Property:

• Vapor Pressure: 0.106mmHg at 25°C
• Boiling Point: 221.6°Cat760mmHg
• Flash Point: 87.8°C
• PSA: 35.33000
• Density: g/cm³
• LogP: 1.24200

Purity/Quality:

98%min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of potassium piperidine-1-dithiocarboxylate

There total 1 articles about potassium piperidine-1-dithiocarboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

piperidine (110-89-4) + carbon disulfide (75-15-0,12122-00-8) → potassium 1-piperidinecarbodithioate (136-04-9)

Guidance literature:

With potassium hydroxide; In ethanol; at 0 ℃; for 1h;

DOI:10.1039/c8dt02965b

Reference yield: 94.0%

potassium 1-piperidinecarbodithioate (136-04-9) + [2-(2-chloro-2-phenyl-acetylamino)-thiazol-4-yl]-acetic acid ethyl ester (294886-87-6) → {2-[2-phenyl-2-(piperidine-1-carbothioylsulfanyl)-acetylamino]-thiazol-4-yl}-acetic acid ethyl ester

Guidance literature:

In ethanol; for 1h; Heating;

DOI:10.1002/ardp.200390002

Reference yield: 90.0%

copper(II) choride dihydrate + potassium 1-piperidinecarbodithioate (136-04-9) → copper(II) bis(pentamethylenedithiocarbamate) (15225-85-1)

Guidance literature:

In methanol; at 20 ℃; for 0.5h;

DOI:10.1039/c8dt02965b

upstream raw materials:

piperidine

carbon disulfide

Downstream raw materials:

2-piperidino-1,3-dithiolium tetraphenylboron

C₂₄H₂₀B^(1-)*C₉H₁₆NOS₂⁽¹⁺⁾

Refernces

• 1、 Turan-Zitouni, Guelhan,Oezdemir, Ahmet,Kaplancikli, Zafer Asim,Chevallet, Pierre,Tunali, Yagmur. "Synthesis and antimicrobial activities of some 1-[(N,N- disubstitutedthiocarbamoylthio)acetyl]-3,5-diaryl-2-pyrazolines". . p. 2717 - 2724. Retrieved 2005.
• 2、 Brustolin,Nardon,Pettenuzzo,Zuin Fantoni,Quarta,Chiara,Gambalunga,Trevisan,Marchiò,Pontisso,Fregona. "Synthesis, chemical characterization and cancer cell growth-inhibitory activities of Cu(ii) and Ru(iii) aliphatic and aromatic dithiocarbamato complexes". . p. 15477 - 15486. Retrieved 2018.
• 3、 Mahfouz, Nadia M.,Moharram, Ahmad M.. "Synthesis, characterization and in-vitro antifungal evaluation of some dithiocarbamic acid derivatives". . p. 315 - 322. Retrieved 1999.