4-Iododibenzo-[b,d]furan

Base Information

• Chemical Name: 4-Iododibenzo-[b,d]furan
• CAS No.: 65344-26-5
• Molecular Formula: C12H7IO
• Molecular Weight: 294.091
• Mol file: 65344-26-5.mol

Synonyms:4-Jod-dibenzofuran;4-iodo-dibenzofuran;4-Iododibenzo-[b,d]furan;Dibenzofuran,4-iodo;

Chemical Property of 4-Iododibenzo-[b,d]furan

Chemical Property:

• Melting Point: 73°C(lit.)
• Boiling Point: 366.6±15.0 °C(Predicted)
• PSA: 13.14000
• Density: 1.809±0.06 g/cm3(Predicted)
• LogP: 4.19060
• Storage Temp.: Keep in dark place,Sealed in dry,Room Temperature

Purity/Quality:

98%,99%, ^*data from raw suppliers

4-Iododibenzofuran >98.0%(GC) ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 4-Iododibenzo-[b,d]furan

There total 6 articles about 4-Iododibenzo-[b,d]furan which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

dibenzofuran (132-64-9,214827-48-2) → 4-Iododibenzo-[b,d]furan (65344-26-5)

Guidance literature:

dibenzofuran; With n-butyllithium; In tetrahydrofuran; at -78 - 20 ℃; for 4h;

With iodine; In tetrahydrofuran; at -78 - 20 ℃; for 2h;

Reference yield: 76.0%

4-dibenzofurylboronic acid (100124-06-9) → 4-Iododibenzo-[b,d]furan (65344-26-5)

Guidance literature:

With copper(I) oxide; ammonium hydroxide; oxygen; potassium iodide; In water; at 25 ℃; for 24h;

DOI:10.1002/chem.201003711

Reference yield: 74.0%

2,3-diethynylbenzo[b]furan → 4-Iododibenzo-[b,d]furan (65344-26-5)

Guidance literature:

With hydrogen iodide; platinum(II) chloride; In water; at 100 ℃; for 1h;

DOI:10.1021/jo0518295

upstream raw materials:

dibenzofuran

chloroform

iodine

4-dibenzofurylboronic acid

Downstream raw materials:

(6-phenyldibenzo[b,d]furan-4-yl)boronic acid

dibenzo-[b,d]furan-4-carbonitrile

N-(dibenzofuran-4-yl)-N-phenyl-amine

Refernces

• 1、 Kang, Yu Jin,Yun, Ju Hui,Han, Si Hyun,Lee, Jun Yeob. "Benzofuroacridine and benzothienoacridine as new donor moieties for emission color management of thermally activated delayed fluorescent emitters". . p. 4573 - 4580. Retrieved 2019/04/25.
• 2、 Amara, Rim,Bentabed-Ababsa, Ghenia,Hedidi, Madani,Khoury, Joseph,Awad, Ha?an,Nassar, Ekhlass,Roisnel, Thierry,Dorcet, Vincent,Chevallier, Floris,Fajloun, Ziad,Mongin, Florence. "Synthesis of N -Aryl and N -Heteroaryl γ-, δ-, and ?-Lactams Using Deprotometalation-Iodination and N -Arylation, and Properties Thereof". . p. 4500 - 4516. Retrieved 2017/09/26.