2-Propenyl-cyclopropane

Base Information

• Chemical Name: 2-Propenyl-cyclopropane
• CAS No.: 4663-23-4
• Molecular Formula: C₆H₁₀
• Molecular Weight: 82.1454
• DSSTox Substance ID: DTXSID201312133
• Nikkaji Number: J881.641G
• Mol file: 4663-23-4.mol

Synonyms:allylcyclopropane;2-propenyl-cyclopropane;4663-23-4;3-Cyclopropyl-1-propene;cyclopropane, 2-propenyl-;2-Propen-1-ylcyclopropane;(prop-2-en-1-yl)cyclopropane;DTXSID201312133;AKOS026730878;EN300-1240841

Chemical Property of 2-Propenyl-cyclopropane

Chemical Property:

• XLogP3: 2.4
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 2
• Exact Mass: 82.078250319
• Heavy Atom Count: 6
• Complexity: 51.1

Purity/Quality:

95% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C=CCC1CC1

Technology Process of 2-Propenyl-cyclopropane

There total 2 articles about 2-Propenyl-cyclopropane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1,5-Hexadien (592-42-7) → cis-bicyclo<2.2.0>hexane (186-04-9,72033-85-3) + bicyclo[2.1.0]pentane (185-94-4) + 2'-propenylcyclopropane (4663-23-4)

Guidance literature:

With mercury; for 96h; Heating; Irradiation;

DOI:10.1039/P29880001371

Reference yield:

bicyclopropyl (5685-46-1) → (2E,4E)-hexa-2,4-diene (5194-51-4) + (E,Z)-2,4-hexadiene (5194-50-3) + ethene (74-85-1) + 2'-propenylcyclopropane (4663-23-4) + buta-1,3-diene (106-99-0,130983-70-9,29406-96-0,9003-17-2) + cyclohexene (110-83-8)

Guidance literature:

at 394 ℃; for 7.5h; Product distribution; Mechanism; pyrolysis of deuterated on one ring BCP; var. temperatures, pressures, and times, IR laser decomposition;

DOI:10.1021/jo00146a006

upstream raw materials:

1,5-Hexadien

bicyclopropyl

Refernces

• 1、 Farneth, William E.,Thomsen, Marcus W.. "Thermal Unimolecular Decomposition of Bicyclopropyl and Deuterated Analogues: Infrared Photoactivation as a Diagnostic Tool in Mechanistic Organic Chemistry". . p. 4851 - 4855. Retrieved 2007/10/02.