TRIHEXYLTETRADECYLPHOSPHONIUM BROMIDE

Base Information

• Chemical Name: TRIHEXYLTETRADECYLPHOSPHONIUM BROMIDE
• CAS No.: 654057-97-3
• Molecular Formula: C32H68P.Br
• Molecular Weight: 563.76000
• European Community (EC) Number: 689-608-0
• ChEMBL ID: CHEMBL3185205
• DSSTox Substance ID: DTXSID0047953
• Mol file: 654057-97-3.mol

Synonyms:Trihexyltetradecylphosphonium bromide;Tetradecyltrihexylphosphonium bromide;

Chemical Property of TRIHEXYLTETRADECYLPHOSPHONIUM BROMIDE

Chemical Property:

• PSA: 13.59000
• Density: 0.96 g/mL at 20oC(lit.)
• LogP: 9.45000
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 28
• Exact Mass: 562.42420
• Heavy Atom Count: 34
• Complexity: 319

Purity/Quality:

98%,99%, ^*data from raw suppliers

Trihexyl(tetradecyl)phosphonium bromide, min. 95% CYPHOS(R) IL 102 ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: CCCCCCCCCCCCCC[P+](CCCCCC)(CCCCCC)CCCCCC.[Br-]
• Uses: Reactant for:? ;Preparation of ionic liquids via solvent-free anion metathesis reaction1? ;Preparation of tetraalkylphosphonium tungstophosphate and isopolytungstate Lindquist cluster anion2 Trihexyltetradecylphosphonium bromide is a phosphonium-based ionic liquid that can be used as a recyclable reaction medium for Heck cross-coupling reactions. It can also be used to prepare supported liquid membranes (SLMs) for gas separation processes.

Technology Process of TRIHEXYLTETRADECYLPHOSPHONIUM BROMIDE

There total 1 articles about TRIHEXYLTETRADECYLPHOSPHONIUM BROMIDE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1-Bromotetradecane (112-71-0) + trihexylphosphine (4168-73-4) → (trihexyl)(tetradecyl)phosphonium bromide (654057-97-3)

Guidance literature:

at 140 ℃; for 24h; Inert atmosphere;

Reference yield: 97.0%

(trihexyl)(tetradecyl)phosphonium bromide (654057-97-3) + bis(trifluoromethane)sulfonimide lithium (90076-65-6) → tetradecyl(trihexyl)phosphonium bistriflamide (460092-03-9)

Guidance literature:

In chloroform; water;

DOI:10.1016/j.tetlet.2012.02.003

upstream raw materials:

1-Bromotetradecane

trihexylphosphine

Downstream raw materials:

tetradecyl(trihexyl)phosphonium bistriflamide

Refernces