Unii-SI7jkx4F22

Base Information

• Chemical Name: Unii-SI7jkx4F22
• CAS No.: 15230-48-5
• Molecular Formula: Cl2Ge H2
• Molecular Weight: 145.512
• European Community (EC) Number: 233-192-1
• DSSTox Substance ID: DTXSID40143425,DTXSID80164992
• Wikidata: Q2331626
• Mol file: 15230-48-5.mol

Synonyms:10060-11-4;GeCl2;UNII-SI7JKX4F22;EINECS 233-192-1;Cl2Ge;Cl2-Ge;DTXSID40143425;DTXSID80164992;CID 6327122;Germanium chloride (GeCl2) (6CI,8CI,9CI);Q2331626

Chemical Property of Unii-SI7jkx4F22

Chemical Property:

• Melting Point: -68°C
• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 0.00000
• Density: g/cm³
• LogP: 1.22320
• Water Solubility.: reac H2O [CRC10]
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 143.8588831
• Heavy Atom Count: 3
• Complexity: 2.8

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: Cl[Ge]Cl

Technology Process of Unii-SI7jkx4F22

There total 5 articles about Unii-SI7jkx4F22 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 14.0%

hydrogenchloride (7647-01-0,15364-23-5) + germane (7782-65-2) → chlorogermane (13637-65-5) + germanium dihydride dichloride (15230-48-5)

Guidance literature:

With AlCl₃; congealing of the products; pumping H2 out; fractionating; transition temp.: -135 - -120 °C (GeH4), -120 - -90 °C (HCl), -83 - -78 °C (H3GeCl) and -61 - -52 °C (H2GeCl2);;

Reference yield:

tetracarbonylgermyl(methylgermyl)iron (122050-25-3) → germane (7782-65-2) + germanium dihydride dichloride (15230-48-5) + {Fe(CO)4(GeH3)(Ge(CH3)ClH)} (121995-42-4) + methylgermyl chloride (29914-10-1) + methylgermane (1449-65-6)

Guidance literature:

With CCl₄; In benzene; under N2, 3-80 days; detn. by (1)H-NMR;

Reference yield:

chlorogermane (13637-65-5) → germanium dihydride dichloride (15230-48-5)

Guidance literature:

With HCl; aluminium trichloride;

upstream raw materials:

tetracarbonylgermyl(methylgermyl)iron

germane

tin(IV) chloride

hydrogenchloride

Downstream raw materials:

hydrogenchloride

hydrogen

germanium

germane

Refernces