N,N-dipentylformamide

Base Information

• Chemical Name: N,N-dipentylformamide
• CAS No.: 26598-27-6
• Molecular Formula: C₁₁H₂₃NO
• Molecular Weight: 185.31
• Mol file: 26598-27-6.mol

Synonyms:N,N-Dipentylformamide;NSC 404527

Chemical Property of N,N-dipentylformamide

Chemical Property:

• Vapor Pressure: 0.00176mmHg at 25°C
• Boiling Point: 293.1°C at 760 mmHg
• Flash Point: 111°C
• Density: 0.863g/cm³

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of N,N-dipentylformamide

There total 10 articles about N,N-dipentylformamide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

tripentylamine (621-77-2) → N,N-dipentylformamide (26598-27-6)

Guidance literature:

With manganese(IV) oxide; oxygen; In chlorobenzene; at 100 ℃; for 4h; under 4500.45 Torr; Autoclave; Green chemistry;

Reference yield: 89.0%

C14H29N (1632121-86-8) → N,N-dipentylformamide (26598-27-6)

Guidance literature:

With tris(2 2'-bipyridyl)ruthenium(II) chloride hexahydrate; oxygen; caesium carbonate; In acetonitrile; at 20 ℃; for 16h; Irradiation; Inert atmosphere;

DOI:10.1055/s-0034-1378205

Reference yield: 53.0%

N1,N1,N2,N2-tetrapentylethane-1,2-diamine (102-80-7) → N,N-dipentylformamide (26598-27-6)

Guidance literature:

With tris(bipyridine)ruthenium(II) dichloride hexahydrate; water; oxygen; silica gel; caesium carbonate; In acetonitrile; at 20 ℃; for 60h; Inert atmosphere; Irradiation;

DOI:10.1016/j.tet.2013.07.056

upstream raw materials:

formic acid

Di-n-amylamine

tripentylamine

carbon monoxide

Refernces

• 1、 -. "A tertiary amine oxidation cracking method of preparing carboxamide". Paragraph 0014; 0023. . Retrieved 2017/08/26.
• 2、 Zhao, Yaohong,Cai, Shunyou,Li, Jing,Wang, David Zhigang. "Visible-light photo-catalytic C-C bond cleavages: Preparations of N,N-dialkylformamides from 1,2-vicinal diamines". supporting information. p. 8129 - 8131. Retrieved 2013/08/28.