naphtho[2,1-a]aceanthrylene

Base Information

• Chemical Name: naphtho[2,1-a]aceanthrylene
• CAS No.: 75519-75-4
• Molecular Formula: C24H14
• Molecular Weight: 302.375
• Mol file: 75519-75-4.mol

Synonyms:

Chemical Property of naphtho[2,1-a]aceanthrylene

Chemical Property:

• Vapor Pressure: 1.12E-11mmHg at 25°C
• Boiling Point: 552.3°Cat760mmHg
• Flash Point: 282°C
• Density: 1.313g/cm³

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of naphtho[2,1-a]aceanthrylene

There total 11 articles about naphtho[2,1-a]aceanthrylene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

2-(9-anthracenyl)-1-naphthyl trifluoromethylsulfonate → naphth<2,1-a>aceanthrylene (75519-75-4)

Guidance literature:

With tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; 1,8-diazabicyclo[5.4.0]undec-7-ene; lithium chloride; tricyclohexylphosphine; In N,N-dimethyl-formamide; at 145 ℃; for 8h; Inert atmosphere; Schlenk technique;

DOI:10.1021/acs.joc.8b00891

Reference yield: 54.0%

C25H15F3O3S → Naphtho<2,3-j>fluoranthene (205-83-4) + naphth<2,1-a>aceanthrylene (75519-75-4)

Guidance literature:

With tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; 1,8-diazabicyclo[5.4.0]undec-7-ene; lithium chloride; tricyclohexylphosphine; In N,N-dimethyl-formamide; at 145 ℃; for 8h; Inert atmosphere; Schlenk technique;

DOI:10.1021/acs.joc.8b00891

Reference yield: 46.0%

anthrone-10-spiro-1'-1'H-benzindazole (75533-58-3) → naphth<2,1-a>aceanthrylene (75519-75-4)

Guidance literature:

With water; sodium chloride; zinc; Heating;

upstream raw materials:

10-hydroxynaphth<2,1-a>aceanthrylene

anthrone-10-spiro-1'-1'H-benzindazole

anthrone-10-spiro-3'-3'H-benzindazole

10-acetoxynaphth<2,1-a>aceanthrylene

Refernces

• 1、 -. "NOVEL COMPOUNDS, ORGANIC LIGHT EMITTING DEVICE DISPLAY AND ORGANIC SOLAR BATTERY USING THE SAME". . . Retrieved 2016/10/08.
• 2、 Hirakawa, Kioyoichi,Toki, Takuya,Yamazaki, Kazuo,Nakazawa, Sho. "Reactions of Spiro-indazoles containing Keto-groups. Syntheses of Benzaceanthrylenes, Naphthaceanthrylenes, and Fluoranthenes". . p. 1944 - 1949. Retrieved 2007/10/02.