CARBONIC ACID ALLYL ETHYL ESTER

Base Information

• Chemical Name: CARBONIC ACID ALLYL ETHYL ESTER
• CAS No.: 1469-70-1
• Molecular Formula: C6H10O3
• Molecular Weight: 130.144
• Hs Code.: 2920909090
• Mol file: 1469-70-1.mol

Synonyms:Carbonicacid, allyl Et ester (5CI);Carbonic acid, allyl ethyl ester (6CI,7CI,8CI);Carbonic acid, ethyl 2-propenyl ester (9CI);Allyl ethyl carbonate;Ethyl2-propenyl carbonate;Ethyl allyl carbonate;

Chemical Property of CARBONIC ACID ALLYL ETHYL ESTER

Chemical Property:

• Refractive Index: 1.4070 to 1.4090
• Boiling Point: 132.7 °C at 760 mmHg
• Flash Point: 45.6 °C
• PSA: 35.53000
• Density: 0.982 g/cm³
• LogP: 1.34550

Purity/Quality:

98%,99%, ^*data from raw suppliers

CarbonicAcidAllylEthylEster ^*data from reagent suppliers

Safty Information:

• Statements: 10
• Safety Statements: 16

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of CARBONIC ACID ALLYL ETHYL ESTER

There total 7 articles about CARBONIC ACID ALLYL ETHYL ESTER which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

chloroformic acid ethyl ester (541-41-3) + allyl alcohol (107-18-6) → allyl ethyl carbonate (1469-70-1)

Guidance literature:

With pyridine; dmap; In dichloromethane; at 0 - 20 ℃; Inert atmosphere;

DOI:10.1021/acs.jmedchem.9b02039

Reference yield: 85.5%

→ allyl ethyl carbonate (1469-70-1)

Guidance literature:

Reference yield: 19.0%

carbon dioxide (124-38-9,18923-20-1) + allyl alcohol (107-18-6) → diallylcarbonate (15022-08-9) + ethyl N,N-diethylcarbamate (3553-80-8) + allyl ethyl carbonate (1469-70-1)

Guidance literature:

With triethylamine; acetylene; at 160 ℃; for 16h;

DOI:10.1246/cl.1996.825

upstream raw materials:

chloroformic acid ethyl ester

allyl alcohol

carbon dioxide

triethylamine

Downstream raw materials:

ethanol

allyl alcohol

Diethyl carbonate

1-(prop-2-enyl)-1,2-dihydropyridine-2-one

Refernces

• 1、 Koike, Kota,Nagano, Masanobu,Ebihara, Masahiro,Hirayama, Tasuku,Tsuji, Mieko,Suga, Hiroaki,Nagasawa, Hideko. "Design, Synthesis, and Conformation-Activity Study of Unnatural Bridged Bicyclic Depsipeptides as Highly Potent Hypoxia Inducible Factor-1 Inhibitors and Antitumor Agents". . p. 4022 - 4046. Retrieved 2020/06/08.
• 2、 Gordillo, Alvaro,Lloyd-Jones, Guy C.. "Pd-catalyzed reaction of allyl carbonate with polyols: The role of CO 2 in transesterification versus etherification of glycerol". supporting information; experimental part. p. 2660 - 2665. Retrieved 2012/04/11.