3-(2-Methoxyethoxy)prop-1-ene

Base Information

• Chemical Name: 3-(2-Methoxyethoxy)prop-1-ene
• CAS No.: 27252-80-8
• Molecular Formula: C₆H₁₂O₂
• Molecular Weight: 116.16
• European Community (EC) Number: 608-068-9
• Nikkaji Number: J1.492.047A
• Mol file: 27252-80-8.mol

Synonyms:3-(2-methoxyethoxy)prop-1-ene;18854-48-3;3-(2-Methoxyethoxy)-1-propene;27252-80-8;1-METHOXY-2-(PROP-2-EN-1-YLOXY)ETHANE;1-Propene,3-(2-methoxyethoxy)-;4,7-Dioxa-1-octene;SCHEMBL1057260;SCHEMBL9907109;Ethylene Glycol Allyl Methyl Ether;1-propene, 3-(2-methoxyethoxy)-;AKOS015900199;FT-0689836

Chemical Property of 3-(2-Methoxyethoxy)prop-1-ene

Chemical Property:

• Vapor Pressure: 17.9mmHg at 25°C
• Melting Point: 10 - 15°C
• Refractive Index: 1.457
• Boiling Point: 120.9°C at 760 mmHg
• Flash Point: 20.5°C
• PSA: 18.46000
• Density: 0.857g/cm³
• LogP: 0.83540
• XLogP3: 0.6
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 5
• Exact Mass: 116.083729621
• Heavy Atom Count: 8
• Complexity: 52.5

Purity/Quality:

99%, ^*data from raw suppliers

Polyglycol AM 500 ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: COCCOCC=C

Technology Process of 3-(2-Methoxyethoxy)prop-1-ene

There total 19 articles about 3-(2-Methoxyethoxy)prop-1-ene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

2-methoxy-ethanol (109-86-4,95507-80-5) + allyl bromide (106-95-6) → monoethylene glycol methyl allyl ether (18854-48-3,27252-80-8)

Guidance literature:

With potassium hydroxide;

DOI:10.1016/S0040-4039(00)88997-2

Reference yield: 97.0%

triethylene glucol monomethyl ether (112-35-6,95507-80-5) + allyl bromide (106-95-6) → allyloxytri(ethylene glycol) monomethyl ether (19685-21-3,27252-80-8)

Guidance literature:

triethylene glucol monomethyl ether; With sodium hydride; In tetrahydrofuran; mineral oil; at 0 ℃; for 0.5h; Inert atmosphere;

allyl bromide; In tetrahydrofuran; mineral oil; at 20 ℃; for 2h; Inert atmosphere;

DOI:10.1002/pola.28924

Reference yield: 92.0%

tetraethylene glycol monomethyl ether (23783-42-8,95507-80-5) + allyl bromide (106-95-6) → 4,7,10,13,16-pentaoxa-1-heptadecene (96220-75-6,27252-80-8)

Guidance literature:

tetraethylene glycol monomethyl ether; With sodium hydride; In tetrahydrofuran; mineral oil; at 20 ℃; for 0.5h; Inert atmosphere;

allyl bromide; In tetrahydrofuran; mineral oil; Inert atmosphere;

DOI:10.1016/j.tetlet.2019.151086

upstream raw materials:

2-methoxy-ethanol

allyl bromide

1,3-dibromo-propane

oxirane

Downstream raw materials:

{3-[2-(2-Methoxy-ethoxy)-ethoxy]-propyl}-diphenyl-phosphane

Bis-{3-[2-(2-methoxy-ethoxy)-ethoxy]-propyl}-phenyl-phosphane

Refernces

• 1、 Tucker-Schwartz, Alexander K.,Farrell, Richard A.,Garrell, Robin L.. "Thiol - Ene click reaction as a general route to functional trialkoxysilanes for surface coating applications". . p. 11026 - 11029. Retrieved 2011.
• 2、 Shin, Hyunseo,Moon, Bongjin. "Careful investigation of the hydrosilylation of olefins at poly(ethylene glycol) chain ends and development of a new silyl hydride to avoid side reactions". . p. 527 - 536. Retrieved 2018/01/27.
• 3、 Sologubov, Semen S.,Markin, Alexey V.,Smirnova, Natalia N.,Novozhilova, Natalia A.,Tatarinova, Elena A.,Muzafarov, Aziz M.. "Thermodynamic Properties of Carbosilane Dendrimers of the Sixth Generation with Ethylene Oxide Terminal Groups". . p. 14527 - 14535. Retrieved 2015/11/23.