Thulium antimonide

Base Information

• Chemical Name: Thulium antimonide
• CAS No.: 12039-33-7
• Molecular Formula: SbTm
• Molecular Weight: 290.684
• European Community (EC) Number: 234-890-9
• Mol file: 12039-33-7.mol

Synonyms:Thulium antimonide;antimony;thulium(3+);EINECS 234-890-9;12039-33-7;Antimony, compound with thulium (1:1);Sb.Tm;Thulium antimonide (TmSb)

Chemical Property of Thulium antimonide

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• Density: g/cm³
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 289.83803
• Heavy Atom Count: 2
• Complexity: 0

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: [Sb].[Tm+3]

Technology Process of Thulium antimonide

There total 6 articles about Thulium antimonide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

thulium (14041-47-5,14041-46-4,14333-45-0,15690-75-2,15720-75-9,15832-57-2,7440-30-4,13598-55-5,13981-30-1) + antimony (7440-36-0) → thulium monoantimonide (12039-33-7)

Guidance literature:

In neat (no solvent); prereaction of starting materials in evacuated Mo-glass ampoules at 500°C for 1 week, pelletizing , heating in a sealed Ta-tube (under vac.) at 1500°C;

DOI:10.1016/0925-8388(94)90774-9

Reference yield:

thulium (14041-47-5,14041-46-4,14333-45-0,15690-75-2,15720-75-9,15832-57-2,7440-30-4,13598-55-5,13981-30-1) + antimony (7440-36-0) → thulium monoantimonide (12039-33-7) + Sb3Tm5, high temperature, orthorhombic

Guidance literature:

In melt; (inert atm.); heating 5:3 mixt. of thulium and antimony at 900°C for 24 h, arc melting; powder XRD;

DOI:10.1021/ic802464u

Reference yield:

thulium (14041-47-5,14041-46-4,14333-45-0,15690-75-2,15720-75-9,15832-57-2,7440-30-4,13598-55-5,13981-30-1) + antimony (7440-36-0) + calcium (7440-70-2) → Ca11Sb10 + thulium monoantimonide (12039-33-7) + Ca3.06Tm0.94Sb3

Guidance literature:

With lead; at 999.84 ℃; for 72h; Inert atmosphere; Glovebox; Sealed tube;

DOI:10.1021/acs.chemmater.1c03300

upstream raw materials:

thulium

antimony

cobalt

iron

Refernces

• 1、 Abdusalyamova, M. N.,Chuiko, A. G.,Golubkov, A. Y.,Popov, S. I.,Parfenova, L. S.,et al.. "Synthesis growth and investigation of the physical-chemical properties of single crystals of TmSb, TmTe and their solid solutions TmSb1-xTex". . p. 107 - 110. Retrieved 1994.
• 2、 Ogunbunmi, Michael O.,Baranets, Sviatoslav,Bobev, Svilen. "Synthesis and Transport Properties of the Family of Zintl Phases Ca3RESb3(RE = La-Nd, Sm, Gd-Tm, Lu): Exploring the Roles of Crystallographic Disorder and Core 4f Electrons for Enhancing Thermoelectric Performance". . p. 9382 - 9392. Retrieved 2021/12/13.