Dioxirane, difluoro-

Base Information

• Chemical Name: Dioxirane, difluoro-
• CAS No.: 96740-99-7
• Molecular Formula: CF2O2
• Molecular Weight: 82.0066
• DSSTox Substance ID: DTXSID30455266
• Nikkaji Number: J648.752A
• Wikidata: Q82277192
• Mol file: 96740-99-7.mol

Synonyms:Dioxirane, difluoro-;difluorodioxirane;3,3-difluorodioxirane;96740-99-7;DTXSID30455266;QDWGHBBFJKJQRE-UHFFFAOYSA-N

Chemical Property of Dioxirane, difluoro-

Chemical Property:

• XLogP3: 0.8
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 0
• Exact Mass: 81.98663556
• Heavy Atom Count: 5
• Complexity: 45.6

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1(OO1)(F)F

Technology Process of Dioxirane, difluoro-

There total 3 articles about Dioxirane, difluoro- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

Fluorocarbonyl hypofluorite (16566-10-2) → Carbonyl fluoride (353-50-4) + difluorodioxirane (96740-99-7)

Guidance literature:

With sulfur dioxide; chlorine monofluoride; cesium fluoride; Multistep reaction. Title compound not separated from byproducts; 1.) neat (no solvent, gas phase), 23 deg C, 0.37 cm³ s^-1, 2.) -196 to -100 deg C;

Reference yield:

Fluorocarbonyl hypofluorite (16566-10-2) → Carbonyl fluoride (353-50-4) + trifluoromethyl hypochlorite (22082-78-6) + difluorodioxirane (96740-99-7)

Guidance literature:

With chlorine monofluoride; cesium fluoride;

Reference yield:

Fluorocarbonyl hypofluorite (16566-10-2) → Carbonyl fluoride (353-50-4) + difluorodioxirane (96740-99-7)

Guidance literature:

With sulfur dioxide; chlorine monofluoride; cesium fluoride; Mechanism; multistep reaction; reaction in the presence of Cl₂ and F₂, respectively, and in the presence of only CsF;

upstream raw materials:

Fluorocarbonyl hypofluorite

Downstream raw materials:

Hexafluoropropene oxide

Carbonyl fluoride

Refernces

• 1、 Russo, Antonio,DesMarteau, Darryl D.. "Difluordioxiran". . p. 956 - 958. Retrieved 2007/10/02.