(1-Propenyl)cyclopropane

Base Information

• Chemical Name: (1-Propenyl)cyclopropane
• CAS No.: 4663-21-2
• Molecular Formula: C₆H₁₀
• Molecular Weight: 82.1454
• Mol file: 4663-21-2.mol

Synonyms:Cyclopropane,1-propenyl- (9CI); Propene, 1-cyclopropyl- (7CI,8CI); 1-Propene,1-cyclopropyl-; 1-Propenylcyclopropane

Chemical Property of (1-Propenyl)cyclopropane

Chemical Property:

• PSA: 0.00000
• LogP: 1.97250

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of (1-Propenyl)cyclopropane

There total 1 articles about (1-Propenyl)cyclopropane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 45.0%

α-Ethylcyclopropanmethanol (18729-46-9) → 1-cyclopropylpropene (4663-21-2)

Guidance literature:

With potassium hydrogensulfate; Heating;

Reference yield: 25.0%

1-cyclopropylpropene (4663-21-2) + acetylium tetrafluoroborate (2261-02-1) → trans-7-fluoro-3-methyl-4-hepten-2-one (94052-68-3,344771-05-7) + 2-methoxy-4-vinyl-2,3-dimethyltetrahydrofuran (94052-69-4) + cis-3-(2-fluorocyclobutyl)-2-butanone (94052-67-2,94132-15-7) + cis-3-(2-fluorocyclobutyl)-2-butanone (94052-67-2,94132-15-7)

Guidance literature:

With methanol; triethylamine; In dichloromethane; pentane; at -60 ℃; Mechanism;

Reference yield:

1-cyclopropylpropene (4663-21-2) + acetylium tetrafluoroborate (2261-02-1) → trans-7-fluoro-3-methyl-4-hepten-2-one (94052-68-3,344771-05-7) + 2-methoxy-4-vinyl-2,3-dimethyltetrahydrofuran (94052-69-4)

Guidance literature:

With methanol; triethylamine; Yield given. Multistep reaction. Yields of byproduct given; 1) pentane-methylene chloride, -30 deg C, 3 min, 2) pentane-methylene chloride, -60 deg C;

upstream raw materials:

α-Ethylcyclopropanmethanol

Downstream raw materials:

trans-7-fluoro-3-methyl-4-hepten-2-one

2-methoxy-4-vinyl-2,3-dimethyltetrahydrofuran

cis-3-(2-fluorocyclobutyl)-2-butanone

cis-3-(2-fluorocyclobutyl)-2-butanone

Refernces