Nitrosyl fluoride

Base Information

• Chemical Name: Nitrosyl fluoride
• CAS No.: 7789-25-5
• Molecular Formula: FNO
• Molecular Weight: 49.0045
• European Community (EC) Number: 232-153-6
• UNII: 9FXL2Q69DQ
• DSSTox Substance ID: DTXSID60228501
• Nikkaji Number: J31.851E
• Wikipedia: Nitrosyl fluoride
• Wikidata: Q2629094
• Mol file: 7789-25-5.mol

Synonyms:nitrosyl fluoride

Chemical Property of Nitrosyl fluoride

Chemical Property:

• Vapor Pressure: 10900mmHg at 25°C
• Melting Point: -132.5°
• Refractive Index: 1.279
• Boiling Point: bp -59.9°
• PSA: 29.43000
• Density: 1.35 g/cm³
• LogP: 0.63730
• Water Solubility.: reacts with H2O to form NO, HNO3, and HF [MER06]
• XLogP3: 0.2
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 0
• Exact Mass: 48.996391786
• Heavy Atom Count: 3
• Complexity: 12.3

Purity/Quality:

99%, ^*data from raw suppliers

NITROSYL FLUORIDE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Chemical Classes: Toxic Gases & Vapors -> Oxidizers
• Canonical SMILES: N(=O)F
• Physical properties: Colorless gas when pure; often appears bluish because of impurities; density 2.176 g/L; liquefies at -56°C; density of liquid 1.326g/mL at its boiling point; solidifies at -134°C; density of solid 1.719 g/cm3; reacts with water.
• Uses: Oxidizer in rocket propellants; stabilizing agent for liquid SO3; fluorinating agent.

Technology Process of Nitrosyl fluoride

There total 51 articles about Nitrosyl fluoride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

iodine heptafluoride (16921-96-3,596797-38-5) + nitrogen(II) oxide (10102-43-9) → iodine pentafluoride + nitrosyl fluoride (7789-25-5) + nitrylfluoride (10022-50-1)

Guidance literature:

at room temp.;

Reference yield:

difluoroether (7783-41-7) + nitrogen(II) oxide (10102-43-9) → nitrosyl fluoride (7789-25-5) + nitrylfluoride (10022-50-1)

Guidance literature:

In neat (no solvent);

Reference yield:

hydrogen fluoride (7664-39-3,12381-92-9,32057-09-3,74835-82-8) + ammonia (7664-41-7) → difluoroamine (10405-27-3) + nitrogen trifluoride (7783-54-2) + nitrosyl fluoride (7789-25-5) + nitrylfluoride (10022-50-1) + N-monofluoroamine (13967-06-1,15861-05-9)

Guidance literature:

In melt; byproducts: N2O, N2, F2; Electrolysis; electrolysis of a molten anhyd. NH3-HF-mixt. (24.5-16% NH3) at 65-40°C;;

upstream raw materials:

trifluoronitrosomethane

tetramethylammonium azide

nitrosylchloride

antimony(III) fluoride

Downstream raw materials:

nitrogen(II) oxide

tin(IV) fluoride

nitrosyl hexafluorophosphate

silicon tetrafluoride

Refernces

• 1、 Stanton,Bien. "SPECTRAL OUTPUT FROM A PREMIXED CHAIN REACTION cw HF LASER.". . p. 3536 - 3540. Retrieved 1980.
• 2、 Pagsberg, Palle,Jodkowski, Jerzy T.,Ratajczak, Emil,Sillesen, Alfred. "Experimental and theoretical studies of the reaction between CF3 and NO2 at 298 K". . p. 138 - 144. Retrieved 1998.
• 3、 Ogai, Amy,Brandon, James,Reisler, Hanna,Suter, Hans Ulrich,Huber, J. Robert,et al.. "Mapping of parent transition-state wave functions into product rotations: An experimental and theoretical investigation of the photodissociation of FNO". . p. 6643 - 6653. Retrieved 1992.
• 4、 Nabiev, Sh. Sh.,Sokolov,Chaivanov. "Vibrational spectra of AuF5 complexes with nitrogen fluorides and oxofluorides". . p. 497 - 505. Retrieved 2013/06/05.
• 5、 Czarnowski. "Kinetics and mechanisms of the thermal gas-phase reactions of CF3OF and CF3OOCF3 with NO2". . p. 83 - 94. Retrieved 2007/10/03.