1,4-Diisopropoxybenzene

Base Information

• Chemical Name: 1,4-Diisopropoxybenzene
• CAS No.: 7495-78-5
• Molecular Formula: C12H18O2
• Molecular Weight: 194.274
• Hs Code.: 2909309090
• NSC Number: 407768
• UNII: 4N5KZZ57YO
• DSSTox Substance ID: DTXSID3064726
• Nikkaji Number: J32.086B
• Wikidata: Q72467356
• Mol file: 7495-78-5.mol

Synonyms:1,4-Diisopropoxybenzene;7495-78-5;1,4-di(propan-2-yloxy)benzene;p-Diisopropoxy Benzene;Benzene, 1,4-bis(1-methylethoxy)-;4N5KZZ57YO;NSC 407768;NSC-407768;NSC407768;UNII-4N5KZZ57YO;P-DIISOPROPOXYBENZENE;SCHEMBL125543;hydroquinone di-isopropyl ether;BENZENE, P-DIISOPROPOXY-;DTXSID3064726;Benzene,4-bis(1-methylethoxy)-;MFCD00128849;AKOS006241635;1,4-BIS(1-METHYLETHOXY)BENZENE;AS-14368;CS-0358044;FT-0657686;A838281

Chemical Property of 1,4-Diisopropoxybenzene

Chemical Property:

• Appearance/Colour: oily light salmon-colored liquid
• Vapor Pressure: 0.0156mmHg at 25°C
• Refractive Index: 1.48
• Boiling Point: 264.8 °C at 760 mmHg
• Flash Point: 93 °C
• PSA: 18.46000
• Density: 0.951 g/cm³
• LogP: 3.26100
• XLogP3: 3.7
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 4
• Exact Mass: 194.130679813
• Heavy Atom Count: 14
• Complexity: 128

Purity/Quality:

98%,99%, ^*data from raw suppliers

1,4-Diisopropoxybenzene ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(C)OC1=CC=C(C=C1)OC(C)C

Technology Process of 1,4-Diisopropoxybenzene

There total 7 articles about 1,4-Diisopropoxybenzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

hydroquinone (123-31-9,8027-02-9) + isopropyl bromide (75-26-3) → Hydrochino-di-isopropylether (7495-78-5)

Guidance literature:

With tetra-(n-butyl)ammonium iodide; potassium carbonate; In acetone; for 24h; Heating;

DOI:10.1021/ol006963k

Reference yield: 58.0%

2-iodo-propane (75-30-9) + hydroquinone (123-31-9,8027-02-9) → Hydrochino-di-isopropylether (7495-78-5)

Guidance literature:

With potassium hydroxide; In water; for 16h; Concentration; Reflux;

Reference yield:

hydroquinone (123-31-9,8027-02-9) → Hydrochino-di-isopropylether (7495-78-5)

Guidance literature:

DOI:10.1016/S0040-4020(01)81329-6

upstream raw materials:

2-iodo-propane

disodium salt of hydroquinone

isopropyl bromide

hydroquinone

Downstream raw materials:

3,6-di-isopropoxy-3,6-dimethoxycyclohexa-1,4-diene

(2,6-di-isopropoxyphenyl)-phosphonigsauredimethylester

(2,5-di-isopropoxyphenyl)-methyl-phosphinsaurechlorid

(2,5-di-isopropoxyphenyl)-methyl-phosphinsauremethylester

Refernces

• 1、 Fuks-Janczarek,Reshak, Ali H.,Kuznik,Kityk,Gabanski,Lapkowski,Motyka,Suwinski. "UV-vis absorption spectra of 1,4-dialkoxy-2,5-bis[2-(thien-2-yl)ethenyl]benzenes". experimental part. p. 394 - 398. Retrieved 2009/04/13.
• 2、 Rathore,Bosch,Kochi. "Selective nitration versus oxidative dealkylation of hydroquinone ethers with nitrogen dioxide". . p. 6727 - 6758. Retrieved 2007/10/02.