Diphenylmercury

Base Information

• Chemical Name: Diphenylmercury
• CAS No.: 587-85-9
• Deprecated CAS: 1337-09-3
• Molecular Formula: C12H10 Hg
• Molecular Weight: 354.801
• European Community (EC) Number: 209-606-1
• NSC Number: 23990
• UNII: 9JF9FUI57J
• DSSTox Substance ID: DTXSID3042130
• Wikipedia: Diphenylmercury
• Wikidata: Q2530372
• Mol file: 587-85-9.mol

Synonyms:DIPHENYLMERCURY;Mercury, diphenyl-;587-85-9;Benzene, mercuriodi-;Diphenylmercury(II);Difenylrtut [Czech];Difenylrtut;EINECS 209-606-1;NSC 23990;UNII-9JF9FUI57J;BRN 0637234;9JF9FUI57J;AI3-17856;DTXSID3042130;NSC-23990;4-16-00-01702 (Beilstein Handbook Reference);DIPHENYL MERCURY;NSC23990;WLN: R-HG-R;C12H10Hg;C12-H10-Hg;DTXCID1022130;Diphenyl mercury (aryl compound);HWMTUNCVVYPZHZ-UHFFFAOYSA-;Tox21_301326;MFCD00002998;AKOS015915698;NCGC00255898-01;CAS-587-85-9;LS-89768;FT-0740374;Q2530372;Diphenylmercury(II), PESTANAL(R), analytical standard;1337-09-3

Chemical Property of Diphenylmercury

Chemical Property:

• Appearance/Colour: White to beige powder
• Melting Point: 124 °C
• Boiling Point: >306°C
• Flash Point: °C
• PSA: 0.00000
• Density: g/cm³
• LogP: 1.71990
• Storage Temp.: Poison room
• Water Solubility.: Insoluble in water.
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 2
• Exact Mass: 356.048894
• Heavy Atom Count: 13
• Complexity: 116

Purity/Quality:

98%min ^*data from raw suppliers

Diphenylmercury(II) ^*data from reagent suppliers

Safty Information:

• Pictogram(s): R26/27/28:Very toxic by inhalation, in contact with skin and if swallowed.; R33:Danger of cumulative effects.; R50
• Hazard Codes: T+,N
• Statements: 26/27/28-33-50/53
• Safety Statements: 13-28-36-45-60-61

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Chemical Classes: Metals -> Metals, Organic Compounds
• Canonical SMILES: C1=CC=C(C=C1)[Hg]C2=CC=CC=C2

Technology Process of Diphenylmercury

There total 119 articles about Diphenylmercury which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

phenyltrifluorosilane (368-47-8) → diphenylmercury(II) (587-85-9,1337-09-3)

Guidance literature:

With mercury(II) oxide; In benzene; byproducts: F3SiOSiF3; addn. of trifluorophenylsilane to a suspn. of HgO in dry benzene, reacting at 25°C for 2 h, pptn.;

DOI:10.1016/0022-328X(88)89077-6

Reference yield: 91.0%

lithium tris(pentafluoroethyl)silylthiolate + phenylmercury(II) chloride (100-56-1) → C12H5F15HgSSi + diphenylmercury(II) (587-85-9,1337-09-3)

Guidance literature:

In diethyl ether; at 20 ℃;

DOI:10.1021/acs.inorgchem.1c02476

Reference yield: 85.0%

phenylmagnesium bromide (100-58-3) → bromo(phenyl)mercury (1192-89-8) + diphenylmercury(II) (587-85-9,1337-09-3) + phenylmercury(II) chloride (100-56-1)

Guidance literature:

With mercury dichloride; In diethyl ether; at 60°C;;

upstream raw materials:

diazomethane

diethyl ether

phenylmercury(II) chloride

bromobenzene

Downstream raw materials:

phenylmercury(II) chloride

Diphenylmethane

benzophenone

biphenyl

Refernces

• 1、 Chen, Guang,Kong, Rong-Mei,Liang, Maosheng,Qu, Fengli,Wang, Hao,Wang, Xiuli,Xia, Lian. "A Boric Acid-Functionalized Lanthanide Metal-Organic Framework as a Fluorescence turn-on Probe for Selective Monitoring of Hg2+ and CH3Hg+". . p. 3366 - 3372. Retrieved 2020/03/10.
• 2、 Karri, Ramesh,Banerjee, Mainak,Chalana, Ashish,Jha, Kunal Kumar,Roy, Gouriprasanna. "Activation of the Hg-C Bond of Methylmercury by [S2]-Donor Ligands". . p. 12102 - 12115. Retrieved 2017/10/24.