Rhenium sulfide (ReS2)

Base Information

• Chemical Name: Rhenium sulfide (ReS2)
• CAS No.: 12038-63-0
• Molecular Formula: ReS₂
• Molecular Weight: 250.339
• European Community (EC) Number: 234-878-3
• DSSTox Substance ID: DTXSID7065201
• Wikipedia: Rhenium_disulfide
• Wikidata: Q4445872
• Mol file: 12038-63-0.mol

Synonyms:(188Re)rhenium sulfide;ReS2;rhenium heptasulfide;rhenium heptasulfide colloid;rhenium sulfide;rhenium-186 heptasulfide

Chemical Property of Rhenium sulfide (ReS2)

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 64.18000
• Density: g/cm³
• LogP: 1.29640
• Water Solubility.: Insoluble in water. Soluble in 1N sodium hydroxide solution.
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 0
• Exact Mass: 250.899895
• Heavy Atom Count: 3
• Complexity: 18.3

Purity/Quality:

98%,99%, ^*data from raw suppliers

Rhenium disulfide Crystal, 99.995% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: S=[Re]=S
• Uses: Rhenium(IV) sulfide is used as a diamagnetic semiconductor. The two dimensional layered inorganic nanomaterials have drawn significant attention recently owing to their thickness dependent physical and chemical properties. They find applications in photocatalysis, photovoltaics, gas sensing, lithium ion batteries, field effect transistors, spintronics etc. Transition metal dischalcogenides represent an important class of inorganic 2D materials having the aforementioned applications.

Technology Process of Rhenium sulfide (ReS2)

There total 22 articles about Rhenium sulfide (ReS2) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

Re2S5 + hydrogen (1333-74-0) → rhenium(IV) sulfide (12038-63-0) + hydrogen sulfide (7783-06-4)

Guidance literature:

at <= 200°C;

Reference yield:

sodium pyrohyporhenate * H2O → rhenium(IV) sulfide (12038-63-0) + sulfur (7704-34-9)

Guidance literature:

With hydrogen sulfide; In sodium hydroxide; dissolving in aq. NaOH, passing H2S into soln.;; pptn, product mixt. obtained;;

Reference yield:

rhenium heptasulfide → rhenium(IV) sulfide (12038-63-0) + sulfur (7704-34-9)

Guidance literature:

In neat (no solvent); decompn. on heating to 250-440 °C in evacuated closed tube;; product identified as ReS2 by X-ray spectroscopy;;

upstream raw materials:

hydrogen

sulfur

sodium sulfide

potassium perrhenate

Refernces

• 1、 Ho,Huang,Chen,Dann,Tiong. "Electronic structure of ReS2 and ReSe2 from first-principles calculations, photoelectron spectroscopy, and electrolyte electroreflectance". . p. 15766 - 15771. Retrieved 1999.
• 2、 Salakhova. "Electrodeposition of thin Re-Se films". . p. 99 - 102. Retrieved 2003.
• 3、 Mironov, Yuri V.,Naumov, Nikolai G.,Kozlova, Svetlana G.,Kim, Sung-Jin,Fedorov, Vladimir E.. "[Re12CS17(CN)6]n- (n = 6, 8): A sulfido-cyanide rhenium cluster with an interstitial carbon atom". . p. 6867 - 6871. Retrieved 2005.
• 4、 Lai, Zhuangchai,Chaturvedi, Apoorva,Wang, Yun,Tran, Thu Ha,Liu, Xiaozhi,Tan, Chaoliang,Luo, Zhimin,Chen, Bo,Huang, Ying,Nam, Gwang-Hyeon,Zhang, Zhicheng,Chen, Ye,Hu, Zhaoning,Li, Bing,Xi, Shibo,Zhang, Qinghua,Zong, Yun,Gu, Lin,Kloc, Christian,Du, Yonghua,Zhang, Hua. "Preparation of 1T′-Phase ReS2 xSe2(1- x) (x = 0-1) Nanodots for Highly Efficient Electrocatalytic Hydrogen Evolution Reaction". . p. 8563 - 8568. Retrieved 2018.
• 5、 Ho,Shen,McConnachie,Kliewer. "Kinetic characterization of unsupported ReS2 as hydroprocessing catalyst". . p. 114 - 122. Retrieved 2010.
• 6、 Lin, Bo,Ma, Bowen,Chen, Jiangang,Zhou, Yao,Zhou, Jiadong,Yan, Xiaoqing,Xue, Chao,Luo, Xiao,Liu, Qing,Wang, Jinyong,Bian, Renji,Yang, Guidong,Liu, Fucai. "Sea-urchin-like ReS2 nanosheets with charge edge-collection effect as a novel cocatalyst for high-efficiency photocatalytic H2 evolution". supporting information. p. 943 - 947. Retrieved 2021/09/02.
• 7、 Xiong, Xin,Yan, Aihua,Zhang, Xiaohui,Huang, Fei,Li, Zhen,Zhang, Zhuoyu,Weng, Haifeng. "ReS2/ZnIn2S4 heterojunctions with enhanced visible-light-driven hydrogen evolution performance for water splitting". . . Retrieved 2021/04/22.