11-Bromo-1-undecanol

Base Information

• Chemical Name: 11-Bromo-1-undecanol
• CAS No.: 1611-56-9
• Molecular Formula: C11H23BrO
• Molecular Weight: 251.207
• Hs Code.: 29055900
• European Community (EC) Number: 216-554-3
• NSC Number: 4029
• UNII: P686BA4MWG
• DSSTox Substance ID: DTXSID00167061
• Nikkaji Number: J195.234J
• Wikidata: Q72513674
• Mol file: 1611-56-9.mol

Synonyms:11-Bromo-1-undecanol;1611-56-9;11-Bromoundecan-1-ol;11-Bromoundecanol;1-Undecanol, 11-bromo-;1-Bromo-11-hydroxyundecane;11-Bromoundecyl Alcohol;C11H23BrO;MFCD00004752;11-Bromo-1-hydroxyundecane;NSC-4029;EINECS 216-554-3;Undecamethylene bromohydrin;NSC4029;11-bromo-l-undecanol;1-Bromo-11-undecanol;11-bromoundecane-1-ol;omega-Bromoundecyl alcohol;11-Bromoundecanyl alcohol;P686BA4MWG;SCHEMBL290960;C11-H23-Br-O;11-Bromo-1-undecanol, 98%;DTXSID00167061;NSC 4029;AKOS015836181;AM84536;CS-W014623;AS-15413;SY011480;B1477;FT-0607211;A51044;EN300-179511;11-Bromo-1-undecanol, purum, >=99.0% (AT);A810234;J-504143

Chemical Property of 11-Bromo-1-undecanol

Chemical Property:

• Appearance/Colour: White to beige crystals or crystalline powder
• Vapor Pressure: 2.8E-06mmHg at 25°C
• Melting Point: 46-49 °C(lit.)
• Refractive Index: 1.476
• Boiling Point: 349.6 °C at 760 mmHg
• PKA: 15.20±0.10(Predicted)
• Flash Point: 122.4 °C
• PSA: 20.23000
• Density: 1.137 g/cm³
• LogP: 3.88450
• Storage Temp.: 0-10°C
• Solubility.: chloroform: soluble50mg/mL, clear to slightly hazy, colorless to
• Water Solubility.: Insoluble in water.
• XLogP3: 5.2
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 10
• Exact Mass: 250.09323
• Heavy Atom Count: 13
• Complexity: 86.2

Purity/Quality:

99% ^*data from raw suppliers

11-?Bromo-?1-?undecanol ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xn
• Hazard Codes: Xn
• Statements: 20/21/22-36/37/38
• Safety Statements: 24/25-36-26

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Chemical Classes: Other Classes -> Halogenated Alcohols
• Canonical SMILES: C(CCCCCO)CCCCCBr
• Uses: 11-Bromo-1-undecanol was used in the preparation of 11-mercapto-1-undecanol and 1-(2-acryloyloxyundecyl)-3-methylimidazolium bromide. It was used in one-pot synthesis of graft copolymers based on a metathesis skeleton with poly(methyl methacrylate) grafts. 11-Bromo-1-undecanol was used in the preparation of 11-mercapto-1-undecanol and 1-(2-acryloyloxyundecyl)-3-methylimidazolium bromide. It was also used in one-pot synthesis of graft copolymers based on a metathesis skeleton with poly(methyl methacrylate) grafts.

Technology Process of 11-Bromo-1-undecanol

There total 21 articles about 11-Bromo-1-undecanol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.2%

BF3 OEt2 + sodium borohydrid + 11-bromoundecanoic acid (2834-05-1) → 1-Bromo-11-hydroxyundecane (1611-56-9)

Guidance literature:

With hydrogenchloride; In tetrahydrofuran; diethylene glycol dimethyl ether; water;

Reference yield: 98.9%

sodium borohydrid + 11-bromo-undecanoic acid methyl ester (6287-90-7) → 1-Bromo-11-hydroxyundecane (1611-56-9)

Guidance literature:

With hydrogenchloride; aluminium trichloride; In diethylene glycol dimethyl ether; water;

Reference yield: 98.0%

11-bromo-undecanoic acid methyl ester (6287-90-7) → 1-Bromo-11-hydroxyundecane (1611-56-9)

Guidance literature:

With lithium aluminium tetrahydride; In diethyl ether; at 0 ℃; for 0.666667h;

DOI:10.1246/bcsj.67.455

upstream raw materials:

9-undecenol

11-bromoundecanoyl chloride

10-undecenyl acetate

11-bromoundecanoic acid ethyl ester

Downstream raw materials:

5,10,15,20-tetrakis<4-(11-hydroxyundecyloxy)phenyl>porphyrin

11-(phenylselanyl)undecan-1-ol

4'-(11-hydroxyundecyloxy)-4-cyanobiphenyl

tris(11-bromo-1-undecyl)benzene-1,3,5-tricarboxylate

Refernces

• 1、 Li,Yong,Aisa. "Synthesis of (Z/E)-11-tetradecen-1-ol, a component of Ostrinia nubilalis sex pheromone". . p. 224 - 226. Retrieved 2008.
• 2、 Regen, Steven L.,Czech, Bronislaw,Singh, Alok. "Polymerized Vesicles". . p. 6638 - 6640. Retrieved 1980.
• 3、 Wube, Abraham,Guzman, Juan-David,Huefner, Antje,Hochfellner, Christina,Blunder, Martina,Bauer, Rudolf,Gibbons, Simon,Bhakta, Sanjib,Bucar, Franz. "Synthesis and antibacterial evaluation of a new series of N-Alkyl-2-alkynyl/(E)-alkenyl-4-(1H)-quinolones". . p. 8217 - 8240. Retrieved 2012.
• 4、 Gurawa, Aakanksha,Kashyap, Sudhir,Kumar, Manoj. "Me3SI-promoted chemoselective deacetylation: a general and mild protocol". . p. 19310 - 19315. Retrieved 2021/06/03.