Phenol, 4,4'-sulfonylbis[2-(2-propenyl)-

Base Information

• Chemical Name: Phenol, 4,4'-sulfonylbis[2-(2-propenyl)-
• CAS No.: 41481-66-7
• Deprecated CAS: 118731-67-2
• Molecular Formula: C18H18 O4 S
• Molecular Weight: 330.405
• Hs Code.: 2908999090
• European Community (EC) Number: 411-570-9
• DSSTox Substance ID: DTXSID9047598
• Nikkaji Number: J60.903J
• Wikidata: Q81984450
• ChEMBL ID: CHEMBL1322154
• Mol file: 41481-66-7.mol

Synonyms:41481-66-7;Phenol, 4,4'-sulfonylbis[2-(2-propenyl)-;bis(3-allyl-4-hydroxyphenyl)sulfone;4-(4-hydroxy-3-prop-2-enylphenyl)sulfonyl-2-prop-2-enylphenol;2,2'-Diallyl-4,4'-sulfonyldiphenol;4,4'-Sulfonylbis[2-(prop-2-en-1-yl)phenol];TGSA;TGSH;DTXSID9047598;Phenol, 4,4'-sulfonylbis(2-(2-propenyl)-;3-Allyl-4-hydroxyphenyl sulfone;EC 411-570-9;Phenol, 4,4'-sulfonylbis(2-(2-propen-1-yl)-;3,3'-diallyl-4,4'-dihydroxydiphenylsulfone;CBMicro_024054;MixCom6_001078;Oprea1_353883;Oprea1_594255;SCHEMBL28231;MLS001207949;CHEMBL1322154;DTXCID7027598;REGID_for_CID_833466;C18H18O4S;CHEBI:189465;4,4'-Sulfonylbis(2-allylphenol);HMS2823N22;bis(3-allyl-4-hydroxyphenyl)sulfon;Tox21_300629;CCG-11232;AKOS000526069;4,4'-Sulfonylbis[2-(2-propenyl)phenol;NCGC00245020-01;NCGC00245020-02;NCGC00254236-01;SMR000504951;BIM-0024107.P001;CAS-41481-66-7;3,3'-Diallyl-4,4'-dihydroxybiphenyl Sulfone;TGSA (4,4'-Sulfonylbis[2-(2-propen-1-yl)phenol]);4-(4-hydroxy-3-prop-2-enylphenyl)sulonyl-2-prop-2-enylphenol;3,3'-Diallyl-4,4'-dihydroxydiphenylsulfone 100 microg/mL in Acetonitrile

Chemical Property of Phenol, 4,4'-sulfonylbis[2-(2-propenyl)-

Chemical Property:

• Melting Point: 138.5 °C(Solv: toluene (108-88-3))
• Boiling Point: 544.5±50.0 °C(Predicted)
• PKA: 7.22±0.20(Predicted)
• Flash Point: 283.1oC
• PSA: 82.98000
• Density: 1.253±0.06 g/cm3(Predicted)
• LogP: 4.46840
• Storage Temp.: -20°C Freezer
• Solubility.: DMSO (Sparingly), Methanol (Slightly)
• XLogP3: 4.1
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 6
• Exact Mass: 330.09258022
• Heavy Atom Count: 23
• Complexity: 468

Purity/Quality:

99.9% ^*data from raw suppliers

TGSH ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xi,N
• Statements: 43-51/53
• Safety Statements: 24-37-61

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C=CCC1=C(C=CC(=C1)S(=O)(=O)C2=CC(=C(C=C2)O)CC=C)O
• Uses: Bis(3-allyl-4-hydroxyphenyl)sulfone has been used in the preparation of microcapsules for light-thermal sensitive imaging system.

Technology Process of Phenol, 4,4'-sulfonylbis[2-(2-propenyl)-

There total 9 articles about Phenol, 4,4'-sulfonylbis[2-(2-propenyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.5%

4,4'-sulfonediphenol (80-09-1,59790-00-0) + allyl tosylate (4873-09-0) → 3,3′-diallyl-4,4′-dihydroxydiphenylsulfone (41481-66-7)

Guidance literature:

With tetrabutyl-ammonium chloride; potassium carbonate; In N,N-dimethyl-formamide; at 110 - 120 ℃; for 8h; Large scale;

Reference yield: 96.2%

4,4’-sulfonylbis((allyloxy)benzene) (41481-63-4) → 3,3′-diallyl-4,4′-dihydroxydiphenylsulfone (41481-66-7)

Guidance literature:

With α-alanine-N-diacetic acid; at 198 - 200 ℃; for 7h; Temperature; Inert atmosphere;

Reference yield: 84.4%

4,4'-sulfonediphenol (80-09-1,59790-00-0) + 3-chloroprop-1-ene (107-05-1) → 3,3′-diallyl-4,4′-dihydroxydiphenylsulfone (41481-66-7)

Guidance literature:

With sodium carbonate; sodium hydroxide; In water; at 95 - 100 ℃; for 5h; Solvent; Reagent/catalyst; Temperature; Autoclave; Large scale;

upstream raw materials:

4,4’-sulfonylbis((allyloxy)benzene)

4,4'-sulfonediphenol

allyl tosylate

3-chloroprop-1-ene

Downstream raw materials:

4,4’-sulfonylbis(2-allyl-1-(allyloxy)benzene)

C₂₄H₃₄O₄S₅

C₃₂H₄₂O₈S₅

Refernces

• 1、 -. "Synthetic method of thermosensitive color developing agent 4,4'- sulfonyl bis [2-(2-propenyl)] phenol". Paragraph 0017-0021. . Retrieved 2019/07/04.
• 2、 -. "Bisphenol-based epoxy compound using thiol-ene reaction and method for preparing the same, and composite of organic-inorganic materials comprising a cured product thereof and method for preparing the composite". Paragraph 0175-0177. . Retrieved 2017/08/24.