Isolongifolol

Base Information

• Chemical Name: Isolongifolol
• CAS No.: 469-27-2
• Molecular Formula: C₁₅H₂₆O
• Molecular Weight: 222.371
• European Community (EC) Number: 207-415-8,214-518-1
• ChEMBL ID: CHEMBL388140
• Nikkaji Number: J38.641C
• Pharos Ligand ID: 617RSQ3K8MM5
• Wikidata: Q110076722
• Mol file: 469-27-2.mol

Synonyms:isolongifolol

Chemical Property of Isolongifolol

Chemical Property:

• Boiling Point: 300.9°Cat760mmHg
• Flash Point: 139.6°C
• PSA: 20.23000
• Density: 0.971g/cm³
• LogP: 3.46730
• XLogP3: 4.4
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 1
• Exact Mass: 222.198365449
• Heavy Atom Count: 16
• Complexity: 296

Purity/Quality:

99% ^*data from raw suppliers

Longifolol ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC1(CCCC2(C3C1C(C2CO)CC3)C)C
• Isomeric SMILES: C[C@]12CCCC([C@@H]3[C@H]1CC[C@@H]3[C@@H]2CO)(C)C

Technology Process of Isolongifolol

There total 8 articles about Isolongifolol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

→ Longifol (469-27-2,1139-17-9,73543-07-4)

Guidance literature:

Longifolen 1, 1.) Diboran-Gas, 2.) H2O2, NaOH;

Reference yield:

→ Longi-β-camphenylylalkohol (469-27-2,1139-17-9,73543-07-4)

Guidance literature:

Longifolen, Pb3O4, Eisessig, Acetanhydrid bei 60grad;

Reference yield:

methyl isolongifolate (13928-57-9,99032-59-4) → (-)-longifolol (469-27-2,1139-17-9,73543-07-4) + (-)-isolongifolol (1139-17-9)

Guidance literature:

With lithium aluminium tetrahydride; In diethyl ether; at 20 ℃; for 12h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;

DOI:10.1021/jo00136a014

upstream raw materials:

longifolene

methyl isolongifolate

Downstream raw materials:

isolongifololaldehyde

Isolongifolic acid

Refernces

• 1、 Vyas, Pramod,Nayak, U. R.. "A Convenient One-pot Hydroboration / Isomerization / Oxidation of Longifolene to Isolongifolol". . p. 337 - 339. Retrieved 2007/10/02.