VANADIUM (IV) CHLORIDE

Base Information

• Chemical Name: VANADIUM (IV) CHLORIDE
• CAS No.: 7632-51-1
• Molecular Formula: Cl4V
• Molecular Weight: 192.754
• Hs Code.: 28273990
• UNII: 2I17MGM5YJ
• Nikkaji Number: J36.577G
• Wikidata: Q421255
• Mol file: 7632-51-1.mol

Synonyms:Vanadiumchloride (VCl4) (8CI); Tetrachlorovanadium; Vanadium tetrachloride;Vanadium(IV) chloride

Chemical Property of VANADIUM (IV) CHLORIDE

Chemical Property:

• Appearance/Colour: red to brown liquid
• Vapor Pressure: 10.173hPa at 25℃
• Melting Point: -28 C
• Boiling Point: 148 - 153 C
• Flash Point: 148.5°C/755mm
• PSA: 0.00000
• Density: 1.816 g/mL at 25 °C(lit.)
• LogP: 2.75800
• Storage Temp.: water-free area
• Sensitive.: Moisture Sensitive
• Solubility.: diethyl ether: slightly soluble(lit.)
• Water Solubility.: soluble alcohol, ether [HAW93]
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 0
• Exact Mass: 192.816418
• Heavy Atom Count: 5
• Complexity: 0

Purity/Quality:

99.9% ^*data from raw suppliers

VANADIUM(IV) CHLORIDE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): 8 (Packing Group: I) UN NO.
• Hazard Codes: T
• Statements: 14-23/24/25-34
• Safety Statements: 26-27-36/37/39-45

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: [Cl-].[Cl-].[Cl-].[Cl-].[V+4]
• Uses: Preparation of vanadium trichloride, vanadium dichloride, and organovanadium compounds.

Technology Process of VANADIUM (IV) CHLORIDE

There total 66 articles about VANADIUM (IV) CHLORIDE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

vanadia + chlorine (7782-50-5) + sulfur (7704-34-9) → disulfur dichloride (10025-67-9) + sulfur dichloride (10545-99-0) + vanadiumtetrachloride (7632-51-1) + vanadium(V) oxychloride (7727-18-6)

Guidance literature:

In neat (no solvent); heating;;

Reference yield:

vanadium(III) sulphide + chlorine (7782-50-5) → disulfur dichloride (10025-67-9) + vanadium(III) chloride (7718-98-1) + vanadiumtetrachloride (7632-51-1)

Guidance literature:

In neat (no solvent); at higher temp.;;

Reference yield:

vanadium(III) sulphide + chlorine (7782-50-5) → disulfur dichloride (10025-67-9) + vanadiumtetrachloride (7632-51-1)

Guidance literature:

In neat (no solvent); slowly heating;;

upstream raw materials:

vanadium

sodium chloride

chlorine

sulfur

Downstream raw materials:

thionyl chloride

vanadium(III) chloride

antimony

vanadium

Refernces

• 1、 Crayton, P. H.,Thompson, W. A.. "". . p. 742 - 743. Retrieved 1963.
• 2、 Troyanov,Shustova,Popov,Sidorov. "Synthesis and structures of C60 fullerene chlorides". . p. 1656 - 1666. Retrieved 2005.
• 3、 Gross, P.,Hayman, C.. "". . p. 45 - 49. Retrieved 1964.
• 4、 Troyanov,Shustova,Popov,Feist,Kemnitz. "Chlorination of C60 and C70 fullerenes using SbCl5 and VCl4 chlorides". . p. 1303 - 1307. Retrieved 2008/10/09.
• 5、 Beattie,Jones,Willson,Young. "Molecular shapes of the first row transition element dichlorides with particular reference to vanadium dichloride". . p. 53 - 62. Retrieved 2008/10/08.