Hexyltriethoxysilane

Base Information

• Chemical Name: Hexyltriethoxysilane
• CAS No.: 18166-37-5
• Deprecated CAS: 329356-67-4
• Molecular Formula: C12H28O3Si
• Molecular Weight: 248.438
• Hs Code.: 29319090
• DSSTox Substance ID: DTXSID40885015
• Nikkaji Number: J1.317.274I
• Wikidata: Q72482439
• Mol file: 18166-37-5.mol

Synonyms:triethoxy(hexyl)silane;18166-37-5;Hexyltriethoxysilane;n-Hexyltriethoxysilane;Silane, triethoxyhexyl-;hexyl triethoxysilane;158808-35-6;C12H28O3Si;Triethoxyhexylsilane;SCHEMBL35784;DTXSID40885015;MFCD00087744;AKOS015839662;FT-0604975;H1158;S09950

Chemical Property of Hexyltriethoxysilane

Chemical Property:

• Appearance/Colour: Clear to straw liquid with mild odor
• Vapor Pressure: 0.411mmHg at 25°C
• Melting Point: < -40 °C
• Refractive Index: 1.408
• Boiling Point: 202.663 °C at 760 mmHg
• Flash Point: 85.937 °C
• PSA: 27.69000
• Density: 0.883 g/cm³
• LogP: 3.61510
• Storage Temp.: Inert atmosphere,Room Temperature
• Sensitive.: Moisture Sensitive
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 11
• Exact Mass: 248.18077129
• Heavy Atom Count: 16
• Complexity: 136

Purity/Quality:

98% ^*data from raw suppliers

N-Hexyltriethoxysilane ^*data from reagent suppliers

Safty Information:

• Pictogram(s): R36/38:Irritating to eyes and skin.
• Hazard Codes: R36/38:Irritating to eyes and skin.
• Statements: 36/37/38-36/38
• Safety Statements: 26-36/37/39-23/26/37

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCCCC[Si](OCC)(OCC)OCC

Technology Process of Hexyltriethoxysilane

There total 10 articles about Hexyltriethoxysilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

1-hexene (592-41-6,25067-06-5) + Triethoxysilane (998-30-1) → hexyltriethoxysilane (18166-37-5)

Guidance literature:

at 90 ℃; for 5h; Inert atmosphere;

Reference yield: 83.0%

ethanol (64-17-5) + hexylsilane (1072-14-6) → hexyltriethoxysilane (18166-37-5)

Guidance literature:

With palladium dichloride; In benzene; at 25 ℃; for 3h;

DOI:10.1016/j.jorganchem.2004.07.048

Reference yield: 68.0%

1-hexene (592-41-6,25067-06-5) + Triethoxysilane (998-30-1) → tetraethoxy orthosilicate (78-10-4) + hexaethoxydisiloxane (2157-42-8) + trans-2-hexene (4050-45-7) + hexyltriethoxysilane (18166-37-5) + β-hexyltriethoxysilane (18166-36-4)

Guidance literature:

With tris(triphenylphosphine)ruthenium(II) chloride; for 5h; Product distribution; Mechanism; Heating; other catalysts; the atmosphere of air or argon;

DOI:10.1016/S0022-328X(00)99230-1

upstream raw materials:

1-hexene

Triethoxysilane

ethanol

tetraethoxy orthosilicate

Downstream raw materials:

diethyl phenylboronate

15-Ethoxy-1,3,5,7,9,11,13,15-octahexyl-2,4,6,8,10,12,14,16,17,18-decaoxa-1,3,5,7,9,11,13,15-octasila-tricyclo[9.5.1.1^3,9]octadecane-5,7,13-triol

1,3,5,7,10-Pentahexyl-2,4,6,8,9,11-hexaoxa-3,7,10-triphospha-1,5-disila-bicyclo[3.3.3]undecane 3,7,10-trioxide

1,5,9,13-Tetrahexyl-3,7,11,15,18,21-hexamethyl-2,4,6,8,10,12,14,16,17,19,20,22-dodecaoxa-3,7,11,15,18,21-hexaphospha-1,5,9,13-tetrasila-tricyclo[11.3.3.3^5,9]docosane 3,7,11,15,18,21-hexaoxide

Refernces

• 1、 Magomedov,G.K.I. et al.. "-". . p. 29 - 36. Retrieved 1978.
• 2、 Abeynayake, Niroshani S.,Donnadieu, Bruno,Gorla, Saidulu,Montiel-Palma, Virginia,Mu?oz-Hernández, Miguel A.,Zamora-Moreno, Julio. "14-Electron Rh and Ir silylphosphine complexes and their catalytic activity in alkene functionalization with hydrosilanes". supporting information. p. 11783 - 11792. Retrieved 2021/09/06.
• 3、 Li, Laiming,Li, Youxin,Assefa, Aschenaki,Bao, James J.. "Preparation, characterization and evaluation of a series of heterogeneous platinum catalysts immobilized on magnetic silica with different acid ligands". . p. 779 - 787. Retrieved 2019/08/12.