3-(9H-Carbazole-9-yl)-9H-carbazole

Base Information

• Chemical Name: 3-(9H-Carbazole-9-yl)-9H-carbazole
• CAS No.: 18628-07-4
• Molecular Formula: C24H16N2
• Molecular Weight: 332.404
• Hs Code.: 2933990090
• Mol file: 18628-07-4.mol

Synonyms:3-(9H-carbazol-9-yl)-9H-carbazole;9H-3,9'-bicarbazole;3,9'-Bi-9H-carbazole;9H-3,9'-biscarbazole;9-(9H-carbazol-3-yl)-9H-carbazole;3-(9H-Carbazole-9-yl)-9H-carbazole;3-(9'-carbazolyl)-9H-carbazole;3-(N-carbazyl)carbazole;

Chemical Property of 3-(9H-Carbazole-9-yl)-9H-carbazole

Chemical Property:

• Melting Point: 212-215℃
• Boiling Point: 598.8±32.0 °C(Predicted)
• PKA: 16.96±0.30(Predicted)
• PSA: 20.72000
• Density: 1.26±0.1 g/cm3(Predicted)
• LogP: 6.41820
• Storage Temp.: Sealed in dry,Room Temperature

Purity/Quality:

3,9''-Bicarbazole ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Uses: 3,9'-Bicarbazole is a useful research chemical.
• Description: 3-(9H-Carbazole-9-yl)-9H-carbazole is a heterocyclic derivative, mainly used as an intermediate for synthetic materials.

Technology Process of 3-(9H-Carbazole-9-yl)-9H-carbazole

There total 33 articles about 3-(9H-Carbazole-9-yl)-9H-carbazole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

3-carbazol-9-yl-9-(p-tolylsulfonyl)carbazole (867248-91-7) → 9-(9H-carbazol-3-yl)-9H-carbazole (18628-07-4)

Guidance literature:

With potassium hydroxide; In tetrahydrofuran; water; dimethyl sulfoxide; for 4h; Heating;

DOI:10.1021/jo702426r

Reference yield: 95.0%

3-carbazolyl-9-acetylcarbazole → 9-(9H-carbazol-3-yl)-9H-carbazole (18628-07-4)

Guidance literature:

With potassium hydroxide; In tetrahydrofuran; water; dimethyl sulfoxide; Reflux;

Reference yield: 92.0%

9-benzyl-3-(9-carbazolyl)-9H-carbazole → 9-(9H-carbazol-3-yl)-9H-carbazole (18628-07-4)

Guidance literature:

With potassium tert-butylate; oxygen; In tetrahydrofuran; dimethyl sulfoxide; for 3h;

upstream raw materials:

9-(4-benzotriazol-1-yl-phenyl)-carbazole

tetrachloromethane

9H-carbazole

3-carbazol-9-yl-9-(p-tolylsulfonyl)carbazole

Downstream raw materials:

4-[3-(9H-carbazol-9-yl)-9H-carbazol-9-yl]benzamide

4-(dicyanomethylene)-2-methyl-6-(p-dimethylaminostyryl)-4H-pyran

2-(4’-((4-(9H-[3,9’-bicarbazol]-9-yl)phenyl)diphenylsilyl)-(1,1’-biphenyl)-4-yl)-1-phenyl-1H-phenanthro[9,10-d]imidazole

3-(3-(9H-[3,9'-bicarbazol]-9-yl)phenyl)-5-phenyl-1,2,4-oxadiazole

Refernces

• 1、 Hong, Jong-In,Huh, Jin-Suk,Kim, Jae-Min,Kim, Jang-Joo,Yang, Dongwook. "The effect of the electron-donor ability on the OLED efficiency of twisted donor-acceptor type emitters". . . Retrieved 2021.
• 2、 -. "Compound for organic luminescence and application thereof". . . Retrieved 2021/03/31.