Tetrabutylammonium nitrite

Base Information

• Chemical Name: Tetrabutylammonium nitrite
• CAS No.: 26501-54-2
• Molecular Formula: C16H36N2O2
• Molecular Weight: 288.47
• European Community (EC) Number: 247-749-1
• DSSTox Substance ID: DTXSID80181088
• ChEMBL ID: CHEMBL1079049
• Mol file: 26501-54-2.mol

Synonyms:Tetrabutylammonium nitrite;26501-54-2;tetrabutylazanium;nitrite;EINECS 247-749-1;1-Butanaminium, N,N,N-tributyl-, nitrite;tetrabutylazanium nitrite;SCHEMBL1271504;CHEMBL1079049;C16H36N.NO2;DTXSID80181088;SHRKDVQQQPFSIY-UHFFFAOYSA-M;C16-H36-N.N-O2;AKOS025212611;AS-67203;FT-0730491;F87259;J-016452

Chemical Property of Tetrabutylammonium nitrite

Chemical Property:

• Melting Point: 99-103oC
• PSA: 52.49000
• LogP: 5.25420
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 12
• Exact Mass: 288.277678395
• Heavy Atom Count: 20
• Complexity: 124

Purity/Quality:

98%,99%, ^*data from raw suppliers

Tetrabutylammonium Nitrite ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: CCCC[N+](CCCC)(CCCC)CCCC.N(=O)[O-]

Technology Process of Tetrabutylammonium nitrite

There total 2 articles about Tetrabutylammonium nitrite which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

tetrabutylammomium bromide (1643-19-2) → tetrabutylammonium nitrite (26501-54-2)

Guidance literature:

With potassium nitrite; In water;

DOI:10.1016/j.tca.2013.01.003

Reference yield:

tetrabutyl ammonium fluoride (429-41-4) → tetrabutylammonium nitrite (26501-54-2)

Guidance literature:

With nitrostyrene; trimethylsilyl cyanide; In tetrahydrofuran; acetonitrile; at 20 ℃; for 5h; Inert atmosphere;

DOI:10.1002/chem.201404780

Reference yield: 100.0%

dinitrogen tetraoxide (10544-72-6) + tetrabutylammonium nitrite (26501-54-2) → tetrabutylammonium nitrate (1941-27-1)

Guidance literature:

In neat (no solvent); stirring (vacuum, 20°C, 30 min), nitrogen oxides evapn. (-10°C, vacuum); recrystn. (ethyl acetate); elem. anal.;

upstream raw materials:

tetrabutylammomium bromide

tetrabutyl ammonium fluoride

Downstream raw materials:

tetrabutylammonium nitrate

naphthalene-1-carboxylic acid butyl ester

nitrogen(II) oxide

Refernces

• 1、 Bhatt, Vasishta D.,Gohil, Kuldip. "Ion exchange synthesis and thermal characteristics of some [N +4444] based ionic liquids". . p. 23 - 29. Retrieved 2013/05/09.