Ammonium 2,4,6-trinitrophenolate

Base Information

• Chemical Name: Ammonium 2,4,6-trinitrophenolate
• CAS No.: 131-74-8
• Molecular Formula: C6H3 N3 O7 . H3 N
• Molecular Weight: 246.136
• Hs Code.: 2923900090
• Wikidata: Q424516
• Mol file: 131-74-8.mol

Synonyms:ammonium 2,4,6-trinitrophenolate;azane;2,4,6-trinitrophenol;picric acid, ammonia salt

Chemical Property of Ammonium 2,4,6-trinitrophenolate

Chemical Property:

• Appearance/Colour: white to light yellow crystal powde
• Melting Point: 277-282 °C (decomp)
• Refractive Index: 1.6500 (estimate)
• Boiling Point: 303.6°Cat760mmHg
• Flash Point: 133.9°C
• PSA: 160.93000
• Density: 1.856g/cm³
• LogP: 3.01030
• Water Solubility.: 1g/100mL H2O (20°C) [MER06]
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 8
• Rotatable Bond Count: 0
• Exact Mass: 246.02364854
• Heavy Atom Count: 17
• Complexity: 292

Purity/Quality:

98%min ^*data from raw suppliers

Safty Information:

• Pictogram(s): A high explosive when dry, flammable when wet.
• Hazard Codes: A high explosive when dry, flammable when wet.

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=C(C=C(C(=C1[N+](=O)[O-])O)[N+](=O)[O-])[N+](=O)[O-].N
• Description: Ammonium picrate is a nitro hydrocarbon derivative. It is composed of yellow crystals with not less than 10% water by mass. Ammonium picrate is highly explosive when dry and a flammable solid when wet, and is slightly soluble in water. The four-digit UN identification number for ammonium picrate with not less than 10% water is 1310. The primary uses are in pyrotechnics and explosives.
• Uses: In explosives, fireworks, rocket propellants.

Technology Process of Ammonium 2,4,6-trinitrophenolate

There total 6 articles about Ammonium 2,4,6-trinitrophenolate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2,4,6-Trinitrophenol (88-89-1) → ammonium picrate (131-74-8)

Guidance literature:

With air; ammonia; water; at 90 ℃;

Reference yield:

2,4,6-Trinitrophenol (88-89-1) → ammonium picrate (131-74-8)

Guidance literature:

With water;

Reference yield:

C40H44N4O2F4*C6H2N3O7(1-)*NH4(1+) → ammonium picrate (131-74-8) + (CH2FC6H3CH2N)4((CH2)4O)2 (340127-71-1)

Guidance literature:

In chloroform-d1; [D₃]acetonitrile; at 25 ℃; Equilibrium constant;

DOI:10.1021/jo0016778

upstream raw materials:

2,4,6-Trinitrophenol

Downstream raw materials:

picramide

isocyanuric acid

Refernces

• 1、 Manjula, Alla,Nagarajan, Madhavarao. "New supramolecular hosts: Synthesis and cation binding studies of novel Troger's base-crown ether composites". . p. 11859 - 11868. Retrieved 2007/10/03.